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Springer, Dordrecht

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10.1016/0378-1119(86)90182-4

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Cationic Transannular Oligomerization Of 1,5-Cyclooctadiene

Authors: Cuiming Yuan, Deyue Yan, Xiangming Xu, Fosong Wang,

Publish Date: 1988
Volume: , Issue:, Pages: 81-85
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Abstract

Cationic transannular oligomerization of 1,5-cyclooctadiene initiated by BF3OEt2 and AlCl3 is presented in this paper. The number-average molecular weight of the resultant polymer is about 1,500, and the softening temperature range is 140–160°C. By means of NMR, IR and PC-MS analyses, the chain structure of poly(l,5-cyclooctadiene) proposed earlier by Marvel et al. is corroborated.


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