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Title of Journal: Oxid Met

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Abbravation: Oxidation of Metals

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Springer-Verlag

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DOI

10.1001/jama.291.12.1445-b

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1573-4889

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Corrosion of CrSubscript2/SubscriptAlC in Ar/1

Authors: Dong Bok Lee Thuan Dinh Nguyen Sang Whan Park
Publish Date: 2011/01/28
Volume: 75, Issue: 5-6, Pages: 313-323
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Abstract

Cr2AlC compounds were synthesized by a powder metallurgical route and corrosion tested at 900 1000 1100 and 1200 °C for up to 150 h under an Ar/1 SO2 gas atmosphere The compounds were resistant to corrosion because a thin αAl2O3 barrier layer quickly formed on the surface which suppressed sulfidation Virtually no sulfur was detected inside the scale except during the initial corrosion stage The superior corrosion resistance of Cr2AlC originated from the high affinity of Al for oxygen to form the thermodynamically stable Al2O3 Unlike Al Cr was not active because Cr was strongly bound to carbon as Cr2C layers in Cr2AlC The small amount of Cr2O3 that had formed was dissolved in the Al2O3 layer The corrosion of Cr2AlC resulted in the formation of an αAl2O3 layer and an underlying Cr7C3 layer


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Other Papers In This Journal:

  1. Beneficial Effect of Pt and of Pre-Oxidation on the Oxidation Behaviour of an NiCoCrAlYTa Bond-Coating for Thermal Barrier Coating Systems
  2. Improving the Physicochemical Properties of Fe–25Cr Ferritic Steel for SOFC Interconnects via Y-Implantation and Y 2 O 3 -Deposition
  3. Oxidation of Heat-resistant Alloys
  4. Corrosion of Three Commercial Steels Under ZnCl 2 –KCl Deposits in a Reducing Atmosphere Containing HCl and H 2 S at 400–500°C
  5. Evaluation of High Temperature Corrosion in Simulated Waste Incinerator Environments
  6. An Improved Treatment of the Kinetics of Coupled Internal Oxidation by a Single Oxidant of the Two Most-Reactive Components of Ternary Alloys and of the Conditions for the Transition to Their External Oxidation
  7. An Improved Treatment of the Kinetics of Coupled Internal Oxidation by a Single Oxidant of the Two Most-Reactive Components of Ternary Alloys and of the Conditions for the Transition to Their External Oxidation
  8. Comparative Study on High Temperature Oxidation of T92 Steel in Dry and Wet Oxyfuel Environments
  9. Quantification of Adherence of Thermal Oxide Scale on Low Carbon Steel Using Tensile Test
  10. The Effect of Different SO 2 /SO 3 Catalytic Media on High-Temperature Corrosion Processes (Hot Corrosion, Fireside Corrosion, Sulfidation–Oxidation)
  11. Isothermal Oxidation Behavior of Ti-50Al Alloy with Y Additions at 800 and 900°C
  12. Isothermal Phase Diagrams of Binary Alloys and Two Oxidants
  13. Photoelectrochemistry of Oxidation Layers: A Novel Approach to Analyze Photocurrent Energy Spectra
  14. Influence of Chromium Carbides on the High Temperature Oxidation Behavior and on Chromium Diffusion in Nickel-Base Alloys
  15. The Mechanism of Phase Transformation in Thermally-Grown FeO Scale Formed on Pure-Fe in Air

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