Characterization of polymer electrolyte membranes

Authors: Bohee Maeng Jungyul Park

Publish Date: 2016/02/22

Volume: 10, Issue: 2, Pages: 118-125

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Abstract

We report studies into the effects of electrolyte membrane characteristics on power generation in glucose fuel cells Commercially available perfluorosulfonate ionomer membranes of various thicknesses were characterized by quantitatively measuring and analyzing electrical power generation Characterization suggested that thinner Nafion® membranes could lead to improved performance higher peak power lower ohmic loss and lower activation loss over thicker membranes however extremely thin membranes gave low performance due to their lack of stability stemming from fabrication failure The dependency on fuel concentration was also identified and a glucose concentration of 1 M gave the best performance Finally the prepared ionexchange polymer composite membrane formed by sorbing a Nafion® membrane into a polycarbonate tracketched PCTE membrane was tested and it was observed that cell performance was remarkably improved when membrane porosity was considered quantitatively Our study is expected to be useful in the design of biofuel cells that can be utilized in lowconcentration environments such as living organisms

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