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Title of Journal: Appl Magn Reson

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Abbravation: Applied Magnetic Resonance

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Springer Vienna

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DOI

10.1002/for.3980120502

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ISSN

1613-7507

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The Role of Metal Ions in the Study of Ancient Pap

Authors: Alfonso Zoleo Daria Confortin Nicola Dal Mina Marina Brustolon
Publish Date: 2010/07/03
Volume: 39, Issue: 3, Pages: 215-223
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Abstract

Samples from covers and endleaves of sixteenth to eighteenth century books in good conservation state from the Biblioteca Nazionale Marciana in Venice have been investigated by means of electron paramagnetic resonance EPR spectroscopy and optical microscopy to characterize the embedded paramagnetic species and to test differences and similarities of the materials in the two types of book components We detected the MnII FeIII and CuII paramagnetic ions and analyzed their EPR signals by comparing them with previous results in literature of EPR studies on paper Interestingly the MnII EPR spectrum profile appears as a fingerprint for samples coming from the same book either from cover or endleaf and it looks different for samples extracted from different books We discuss the role of EPR as a spectroscopic tool for characterizing the interaction of the ions with the paper components and as possible agents of degradationWe are deeply thankful to Dr Silvia Pugliese for providing the paper samples from Biblioteca Nazionale Marciana and for reviewing the article We are also very grateful to Prof Carlo Federici former director of Istituto di Patologia del Libro Rome for the helpful discussions suggestions and reviewing


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  1. EPR Spectra of Transition-Metal Proteins: the Benefits of Data Deposition in Standard Formats
  2. A Superconducting Quantum Interference Device Measurement System for Ultra Low-Field Nuclear Magnetic Resonance
  3. Use of Oxygen Gas in the Low-Temperature Time-Resolved EPR Experiments
  4. Features of spin exchange in nitroxide biradicals in the ionic liquid bmimPF 6
  5. Influence of Compression on Magnetic Properties of Nickel Chloride Coordination Compound with 3-Amino-4-Ethoxycarbonylpyrazole
  6. EPR and SEM study of organo-mineral associations in Lower Permian evaporite dolomites
  7. EPR Study of Ligand Effects in Spin Triads of Bis( o -Semiquinonato)Copper(II) Complexes
  8. Molecular Motion in Frozen Phospholipid Bilayers in the Presence of Sucrose and Sorbitol Studied by the Spin-Echo EPR of Spin Labels
  9. Variable Coupling Scheme for High-Frequency Electron Spin Resonance Resonators Using Asymmetric Meshes
  10. Application of Different Spectral Methods to Examine Structure of the Complexes Found in the Cycloaddition Reactions of 4-Trifluoromethylbenzonitrile Oxide to Olefins
  11. Electron Paramagnetic Resonance and Electron Spin Echo Studies of Co 2+ Coordination by Nicotinamide Adenine Dinucleotide (NAD + ) in Water Solution
  12. Broadband Continuous Nuclear Magnetic Resonance Signal in a Pulsed Magnetic Field: Numerical Solutions of Bloch Equations under Radio Frequency Irradiation
  13. Absolute Quantification Using Turbo Spectroscopic Imaging in Multiple Sclerosis Patients
  14. Magnetic Resonance and Optical Spectroscopy of Yb 3+ in CsCaF 3 Single Crystal: an Analysis of Distortions of the Crystal Lattice near Yb 3+
  15. Comparison of Four X-Band TE 111 Cavities for In Vivo ESR Tooth Dosimetry
  16. EPR Technology Spectroscopic Investigation of Generation of Reactive Oxygen Species Free Radicals in Laccase-Activated Jute Fiber
  17. Resolving Conformational and Rotameric Exchange in Spin-Labeled Proteins Using Saturation Recovery EPR
  18. Nuclear Spin-Flip Satellites in Electron Paramagnetic Resonance Spectroscopy
  19. Co 2+ Ions in ZnO powders as seen by Magnetic Resonance

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