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Title of Journal: Contrib Mineral Petrol

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Abbravation: Contributions to Mineralogy and Petrology

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Springer Berlin Heidelberg

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1432-0967

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Trace element mapping by LAICPMS assessing geoc

Authors: Tom Raimondo Justin Payne Benjamin Wade Pierre Lanari Chris Clark Martin Hand
Publish Date: 2017/03/16
Volume: 172, Issue: 4, Pages: 17-
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Abstract

A persistent problem in the study of garnet geochemistry is that the consideration of major elements alone excludes a wealth of information preserved by trace elements particularly the rareearth elements REEs This is despite the fact that trace elements are generally less vulnerable to diffusive resetting and are sensitive to a broader spectrum of geochemical interactions involving the entire mineral assemblage including the growth and/or dissolution of accessory minerals We outline a technique for the routine acquisition of highresolution 2D trace element maps by LAICPMS and introduce an extension of the software package XMapTools for rapid processing of LAICPMS data to visualise and interpret compositional zoning patterns These methods form the basis for investigating the mechanisms controlling geochemical mobility in garnet which are argued to be largely dependent on the interplay between element fractionation mineral reactions and partitioning and the length scales of intergranular transport Samples from the Peaked Hill shear zone Reynolds Range central Australia exhibit contrasting trace element distributions that can be linked to a detailed sequence of growth and dissolution events Trace element mapping is thus employed to place garnet evolution in a specific paragenetic context and derive absolute age information by integration with existing U–Pb monazite and Sm–Nd garnet geochronology Ultimately the remarkable preservation of original growth zoning and its subtle modification by subsequent reequilibration is used to ‘see through’ multiple superimposed events thereby revealing a previously obscure petrological and temporal record of metamorphism metasomatism and deformationWe are greatly indebted to the developers of Iolite http//iolitesoftwarecom/ in particular Bence Paul and Chad Paton for their assistance with method development and data processing Detailed and constructive reviews from three anonymous reviewers improved several aspects of this manuscript and we are grateful to Othmar Müntener for editorial handling The MON GT garnet standard used in this study was kindly provided by Chris Harris Funding for this work was provided by ARC Discovery Grants DP160103449 to TR and DP160104637 to MH and CC


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Other Papers In This Journal:

  1. Precise estimation of pressure–temperature paths from zoned minerals using Markov random field modeling: theory and synthetic inversion
  2. Formation of cordierite-bearing lavas during anatexis in the lower crust beneath Lipari Island (Aeolian arc, Italy)
  3. An Early Cretaceous garnet pressure–temperature path recording synconvergent burial and exhumation from the hinterland of the Sevier orogenic belt, Albion Mountains, Idaho
  4. Crystal reaming during the assembly, maturation, and waning of an eleven-million-year crustal magma cycle: thermobarometry of the Aucanquilcha Volcanic Cluster
  5. Origin of phlogopite-orthopyroxene inclusions in chromites from the Merensky Reef of the Bushveld Complex, South Africa
  6. An empirical garnet (YAG) – xenotime thermometer
  7. Magma storage and mixing conditions for the 1953–1974 eruptions of Southwest Trident volcano, Katmai National Park, Alaska
  8. In situ Re–Os isotopic analysis of platinum-group minerals from the Mayarí-Cristal ophiolitic massif (Mayarí-Baracoa Ophiolitic Belt, eastern Cuba): implications for the origin of Os-isotope heterogeneities in podiform chromitites
  9. Reply to comments by Sengupta, Raith and Dasgupta on S. B. Bhattacharya and R. K. Kar (2002)
  10. Metasomatized lithospheric mantle beneath Turkana depression in southern Ethiopia (the East Africa Rift): geochemical and Sr–Nd–Pb isotopic characteristics
  11. In situ observations of bubble growth in basaltic, andesitic and rhyodacitic melts
  12. NanoSIMS mapping and LA-ICP-MS chemical and U–Th–Pb data in monazite from a xenolith enclosed in andesite (Central Slovakia Volcanic Field)
  13. Phosphorus-controlled trace element distribution in zircon revealed by NanoSIMS
  14. Hydroxyl in olivines from mantle xenoliths in kimberlites of the Siberian platform
  15. Electrical conductivity of orthopyroxene and plagioclase in the lower crust
  16. Chromite in komatiites: 3D morphologies with implications for crystallization mechanisms
  17. In situ Sr isotopic analyses of epidote: tracing the sources of multi-stage fluids in ultrahigh-pressure eclogite (Ganghe, Dabie terrane)
  18. Source components of the Gran Canaria (Canary Islands) shield stage magmas: evidence from olivine composition and Sr–Nd–Pb isotopes
  19. The stability and origin of sodicgedrite in ultrahigh-temperature Mg-Al granulites: a case study from the Gondwana suture in southern India
  20. Plagioclase in the Skaergaard intrusion. Part 1: Core and rim compositions in the layered series
  21. The Campanian Ignimbrite (southern Italy) geochemical zoning: insight on the generation of a super-eruption from catastrophic differentiation and fast withdrawal
  22. Melting of clinopyroxene + magnesite in iron-bearing planetary mantles and implications for the Earth and Mars
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  24. Experimental calibration of a garnet–clinopyroxene geobarometer for mantle eclogites
  25. A case for hornblende dominated fractionation of arc magmas: the Chelan Complex (Washington Cascades)
  26. Melting phase relations of a mica–clinopyroxenite from the Milk River area, southern Alberta, Canada
  27. Shoshonite and sub-alkaline magmas from an ultrapotassic volcano: Sr–Nd–Pb isotope data on the Roccamonfina volcanic rocks, Roman Magmatic Province, Southern Italy
  28. The role of slab melting in the petrogenesis of high-Mg andesites: evidence from Simbo Volcano, Solomon Islands
  29. Evolution of the Taupo Volcanic Center, New Zealand: petrological and thermal constraints from the Omega dacite
  30. Multi-stage metasomatism of diamondiferous eclogite xenoliths from the Udachnaya kimberlite pipe, Yakutia, Siberia
  31. Hercynian, Pan-African, Proterozoic and Archean ion-microprobe zircon ages for a Betic-Rif core complex, Alpine belt, W Mediterranean – consequences for its P - T - t path

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