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Title of Journal: Rheol Acta

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Abbravation: Rheologica Acta

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Springer-Verlag

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DOI

10.1002/jbm.a.33228

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1435-1528

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Rheological and morphological properties of PA6/EC

Authors: Ehsan Taghizadeh Ghasem Naderi Charles Dubois
Publish Date: 2010/08/21
Volume: 49, Issue: 10, Pages: 1015-1027
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Abstract

Polyamide6/polyepichlorohydrin co ethylene oxide PA6/ECO nanocomposites were prepared with 6 wt organoclay and different ECO content from 5 to 40 wt via twostep melt blending process The effects of organoclay and rubber content on the morphological and rheological properties of samples have been studied Samples have been characterized by Xray diffraction XRD scanning electron microscopy SEM and rheometry in small amplitude oscillatory shear XRD results indicate that the nanoclay platelets are partially exfoliated in both PA6 and ECO phases The higher rubber content of nanocomposite samples results in higher exfoliation degree of the nanoclay layers SEM photomicrographs of samples show that the size of rubber droplets increases by the introducing of nanoclay Oscillatory shear measurements show that the storage modulus of nanocomposite samples significantly increases in comparison with unfilled blends The formation of physical network is the prime cause of such increase Moreover presence of nanoclay dramatically increases melt yield stress of the samples Palierne emulsion model has been applied to predict the rheological behavior of unfilled blends A quantitative agreement between Palierne model and those of experimental data is found for low ECO content samples


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  2. Amorphous and crystalline states of ultrasoft colloids: a molecular dynamics study
  3. A hierarchical multi-mode MSF model for long-chain branched polymer melts part II: multiaxial extensional flows
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  5. Can dynamical mechanical measurements predict brittle fracture behaviour?
  6. Self-reinforcement of polymers as a consequence of elongational flow
  7. The role of convective constraint release in parallel superposition flows of nearly monodisperse entangled polymer solutions
  8. Influence of the initial cooling temperature on the gelation and yield stress of waxy crude oils
  9. Molecular architecture and linear viscoelasticity of homogeneous ethylene/styrene copolymers
  10. Flow analysis of the weld line formation during injection mold filling of thermoplastics
  11. Squeeze flow of soft solids between rough surfaces
  12. Molecular orientation in non-Newtonian flow of dilute polymer solutions around spheres
  13. The contribution of frictional contacts to the shear strength of coarse glass bead powders and slurries
  14. End effects in rotational viscometry II. Pseudoplastic fluids at elevated Reynolds number
  15. Rheological behaviour of a high-melt-strength polypropylene at elevated pressure and gas loading for foaming purposes
  16. The effect of premature wall yield on creep testing of strongly flocculated suspensions
  17. Orientation distribution in injection molding: a further step toward more accurate simulations
  18. Fractal analysis of viscoelastic data with automated gel point location and its potential application in the investigation of therapeutically modified blood coagulation
  19. Modeling confinement in polymer nanocomposites from linear viscoelasticity data
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  21. On exact solutions of the flow equations for Bingham visco-plastic fluids through an eccentric annular cross-section
  22. A computational extensional rheology study of two biofluid systems
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  29. An error-minimizing approach to inverse Langevin approximations

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