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Title of Journal: J Coat Technol Res

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Abbravation: Journal of Coatings Technology and Research

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Springer US

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DOI

10.1007/978-3-319-40667-1_20

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1935-3804

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Effect of acid value on the esterification mechani

Authors: Ericka N J Ford James W Rawlins Sharathkumar K Mendon Shelby F Thames
Publish Date: 2012/05/30
Volume: 9, Issue: 5, Pages: 637-641
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Abstract

Aqueous solutions of maleinized soybean oil MSO were evaluated as formaldehydefree reagents for cellulosic textiles The reactivity of cotton cellulose with MSO reagents having acid values of 156 and 230 mg KOH/g neutralized with aqueous ammonia in excess of functional groups was studied using diffuse reflectance infrared Fourier transform spectroscopy The acid value of aqueous ammonianeutralized MSO influenced the formation of protonated amide intermediates Cyclic anhydride and protonated amide functional groups were identified as reaction intermediates which resulted in carboxylic ester linkages between MSO and cellulose upon elevated temperature curingThe authors gratefully acknowledge the support received from the Cooperative State Research Education and Extension Service the US Department of Agriculture Agreement No 20013820210424 The authors also thank David Delatte for synthesizing the maleinized soybean oil investigated in this study


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  2. Stress development and film formation in multiphase composite latexes
  3. The impact of solvent characteristics on performance and process stability of printed carbon resistive materials
  4. Chemical and anticorrosion characterization of polysilsesquioxane coatings catalyzed by different acids
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  6. Surface treatment optimization of pigmentary TiO 2 from an industrial aspect
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  8. CNSL: an environment friendly alternative for the modern coating industry
  9. Nondestructive analysis of uneven paint coatings by dynamic heat conduction following flash heating
  10. A review of solid-state lighting and its impact on the marketing and production of decorative coatings
  11. Low-temperature fabrication of TiO 2 film on flexible substrate by atmospheric roll-to-roll CVD
  12. Scratch behavior of nano-alumina/polyurethane coatings
  13. Kinetics analysis and physical properties of photocured silicate-based thiol-ene nanocomposites: The effects of vinyl POSS ene on the polymerization kinetics and physical properties of thiol-triallyl ether networks
  14. The effect of hydrogen shielding gas on microstructure and abrasive wear behavior in the surface modification process using the tungsten inert gas method
  15. Use of novel polyetheralkanolamine comb polymers as pigment dispersants for aqueous coating systems
  16. Analysis of transparent conductive silver nanowire films from dip coating flow
  17. Synthesis and evaluation of functional polymeric additives with urethane linkage as dispersing agents for preparation of pigment concentrates with high solid loading, low-VOC content, and usefulness for industrial coatings
  18. Hybrid organic/inorganic coatings produced using a dual-cure mechanism

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