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Title of Journal: Transition Met Chem

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Abbravation: Transition Metal Chemistry

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Springer Netherlands

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ISSN

1572-901X

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Intermediates in reactions of the diimine complex

Authors: Michael J Blandamer John Burgess Paul Wellings
Publish Date: 2013/12/03
Volume: 6, Issue: 6, Pages: 364-367
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Abstract

Kinetic and spectroscopic observations are reported for the reaction of trisferrozineironII with hydroxide in DMSO and DMFH2O mixtures and with cyanide in MeOH and DMSOH2O mixtures Micellar effects CTAB are described for the reactions of trisferrozineironII and of tris5sulphonato110phenanthrolineironII with hydroxide Results for the ferrozine complex are discussed in terms of mechanisms involving intermediates formed by attack of hydroxide or cyanide at the coordinated ligand

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  1. Synthesis, structures and magnetic properties of three metal-organic frameworks containing manganese(II)
  2. Synthesis and X-ray crystal structures of a series of 3d–4f lanthanide complexes: lanthanide(III)–copper(II) coordination polymers with 2,5-pyridinedicarboxylic acid ligand
  3. A novel series of nickel(II)-dppe-arylazoimidazole complexes. Synthesis and spectroscopic characterization
  4. Gold(I)-Gold(III)-4,4′-bpy-phosphine complexes: Synthesis and multinuclear NMR study
  5. A copper(II) complex of the Schiff base from l -valine and 2-hydroxy-1-naphthalidene plus 1,10-phenanthroline: synthesis, crystal structure, and DNA interaction
  6. Biophysical, spectroscopic and biochemical investigation of DNA–Cu(II)-GSH interactions
  7. Kinetics and mechanism of substitution of iron(II)–triazine complexes by 1,10-phenanthroline
  8. Three coordination polymers constructed from bis(imidazol-l-yl-methyl)benzene: syntheses, structures, and third-order nonlinear optical properties
  9. Synthesis and photophysical characterization of ruthenium(II) and platinum(II) complexes with bis-pyridylethynyl-phenanthroline ligands as a metalloligand
  10. DNA binding and photocleavage properties of two mixed-ligand oxovanadium complexes
  11. Infrared and Raman spectroscopic characterization of the phosphate mineral kosnarite KZr 2 (PO 4 ) 3 in comparison with other pegmatitic phosphates
  12. Outer-Sphere electron-transfer and the effect of linkage isomerism in the titanium(III) reduction of nitro-pentacyanocobaltate(III) and nitro-, and nitrito-pentaamminecobalt(III) complexes in aqueous acidic media
  13. A series of trinuclear sandwich-like cyanide-bridged iron(III)-manganese(II) complexes: synthesis, crystal structures, and magnetic properties
  14. Synthesis and physico-chemical studies on transition metal complexes of symmetric bis -Schiff base ligands
  15. Exchange coupling in di-μ-hydroxo-bridged chromium(III) dimers
  16. Inner sphere oxidation of N , N ′-ethylenebis(isonitrosoacetyleacetoneimine)copper(II) by N -bromosuccinimide in aqueous weakly acidic solutions
  17. Initial state and transition state solvation in substitution at the square-planar complexes, [PtCl 4 ] 2− and [Pd(Et 4 dien)Cl] +
  18. Detection of single nucleotide polymorphisms by the specific interaction between transition metal ions and mismatched base pairs in duplex DNA
  19. Catalysis of the coupling reaction of aryl chlorides with bis(pinacolato)diboron by tricyclohexylphosphine-cyclopalladated ferrocenylimine complexes
  20. Ruthenium(III) – catalyzed oxidative cleavage of p -aminoazobenzene by chloramine-B in alkaline medium and uncatalyzed reaction in acid medium: spectrophotometric kinetic and mechanistic study
  21. An oxovanadium(IV) complex of an l -serine Schiff base and 1,10-phenanthroline: synthesis, crystal structure, and DNA and albumin-binding properties
  22. Mössbauer study of some iron(III) complexes with urea type ligands and the crystal structure of hexakisdimethylureairon(III) perchlorate
  23. Preparation and characterization of Co(II), Ni(II) and Cu(II) complexes of a ligand containing 1,3,4-thiadiazole groups
  24. Syntheses, crystal structures, and magnetic and fluorescence properties of three complexes of mixed flexible N,N′-bis(3-pyridylmethyl)amine and rigid pyromellitate ligands
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