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Title of Journal: Chin J Polym Sci

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Abbravation: Chinese Journal of Polymer Science

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Springer Berlin Heidelberg

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DOI

10.1016/0083-6656(75)90118-x

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ISSN

1439-6203

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Suspension polymerization of methyl methacrylate s

Authors: Baiyu Li Yinping Wang Xiaobin Niu Zaiman Liu
Publish Date: 2014/01/03
Volume: 32, Issue: 2, Pages: 123-129
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Abstract

A kind of fibrous clay palygorskite PAL was used as the sole stabilizer in suspension polymerization without the using of any other stabilizer usually used especially polymeric stabilizers In order to improve the compatibility with the organic monomer PAL nano fibers were organically modified with silane coupling agent methacryloxypropyltrimethoxysilane MPS Transmission electron microscopy TEM and Fouriertransform infrared FTIR spectroscopy results show that the hydrolyzed MPS was attached onto PAL surface through SiOSi bonds formation without morphology change of PAL At a loading amount of PAL to monomer as low as 036 wt effective stabilization could be achieved After suspension polymerization spherical polymethyl methacrylate PMMA particles were obtained Scanning electron microscopy SEM analysis on both the outer surface and the inner cracked surface of the spherical PMMA particles indicates that the PAL particles reside on the surface of the PMMA spheres The densely stacked PAL together with attached silane coupling agent stabilized the droplets throughout the suspension polymerization


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  2. Toughening of polycarbonate through reactive melt blending: Effect of hydroxyl content and viscosity of hydroxyl-terminated polydimethysiloxane
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  6. Triphenylphosphine as reducing agent for copper(II)-catalyzed AGET ATRP
  7. Electrospinning of cyclodextrin functionalized chitosan/PVA nanofibers as a drug delivery system
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  9. Electrosyntheses and characterization of a fluorescent conducting copolymer of benzanthrone and thiophene
  10. Supercritical CO 2 assisted preparation of open-cell foams of linear low-density polyethylene and linear low-density polyethylene/carbon nanotube composites
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  14. Synthesis and properties of copolymers containing cucurbit[6]uril-based pseudorotaxane structure
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  16. Continuous stiffness mode nanoindentation response of poly(methyl methacrylate) surfaces

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