Authors: Pan Ma Liang Lv Min Zhang Qing Yuan Jiantao Cao Changhua Zhu
Publish Date: 2015/07/24
Volume: 22, Issue: 6, Pages: 1567-1571
Abstract
A novel diimidelinked ironIII containing porous organic polymer FePPOP was designed and synthesized by the raisebyonestory method using ironIIItetraaminophthalocyanine and 34910perylene tetracarboxylic dianhydride The yielded polymer has been fully characterized by IR Xray diffraction scanning electron microscopy thermal gravimetric analysis and nitrogen sorption isotherm measurements FePPOP has unique morphological properties eg amorphous insoluble multilayered microporous structure It also served as an efficient heterogeneous catalyst in the oxidation reaction of benzyl alcohol to benzaldehyde under mild reaction condition with a large turnover number as high as 960 The present work showcased a group of structure–function relationship among molecular structure porous organic polymer structure and catalyst functional properties It would attract great research interest in the catalysis applications of a new class of porous organic polymers in organic reactions
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