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Title of Journal: J Fusion Energ

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Abbravation: Journal of Fusion Energy

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Springer US

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DOI

10.1002/ncr.4110070403

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ISSN

1572-9591

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Reaction Kinetics for the Synthesis of LiSubscrip

Authors: Maoqiao Xiang Yingchun Zhang Yun Zhang Wei Liu Chaofu Wang Yonghong Yu
Publish Date: 2016/03/11
Volume: 35, Issue: 4, Pages: 652-659
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Abstract

Currently Li4SiO4 has been considered one of the best candidates for tritium breeders Besides it has also been suggested to be the promising hightemperature carbon dioxide CO2 solid sorbent and lithium ion conducting material As the knowledge of reaction kinetics can offer either a practical or theoretical purpose for predicting and optimizing the reaction process the kinetics of formation of Li4SiO4 from Li2CO3 and Li2SiO3 were investigated by nonisothermal thermogravimetric technique at four different heating rates The Malek method results showed that the reaction was the Avarami–Erofeev model ie at about 650 °C the Li2SiO3 and Li2CO3 with molar ratio of 11 formed Li4SiO4 crystal nucleus randomly and then it grew by the diffusion of Li and O through Li4SiO4 layer And the diffusion stage was the rate controlling step The performances of Li4SiO4 pebbles fabricated by a graphite bed process using Li2SiO3 and Li2CO3 were also evaluatedThis work has been financially supported by the National Natural Science Foundation of China Nos 51372017 and 51172019 International Thermonuclear Experimental Reactor ITER Project of China No 2014GB123000 and National Magnetic Confinement Fusion Energy Research Project No 2015GB121006


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Other Papers In This Journal:

  1. Erratum to: The Study of the Dynamics of Z Pinch Plasma Using Electromagnetic, Thermal and Circuital Coupling
  2. Design and Fabrication of a Data Acquisition System for Pulsed Neutron Flux Measurement of Plasma Focus Devices
  3. Investigation of Arc Regulation of Hot Cathode Ion Source with Langmuir Probe
  4. Comments to the Article “The Behavior of Radial Electric Field and Toroidal Rotation in the Edge Plasma of Divertor Tokamak” by A. H. Bekheit Published in J. Fusion Energy (2010) 29, p. 443–446
  5. Evaluation of Heat Transfer Augmentation in a Nanofluid-Cooled Microchannel Heat Sink
  6. Measurement of Plasma Energy Confinement Time in Presence of Resonant Helical Field in IR-T1 Tokamak
  7. On the Current Sharing Control of ITER Poloidal Field Converter
  8. Thermalization of Langmuir Wave Energy via the Stochastic Plasma Electron Acceleration
  9. Combined Effect of Ion Temperature and Magnetic Field on Collisionless Sheath Structure
  10. The Use of Plasma Actuators in Narrowband Active Noise Control
  11. Effect of Internal Breeding of Tritium and Helium-3 on the Ignition of an ICF Fuel Pellet
  12. Condensed Atomic Hydrogen as a Possible Target in Inertial Confinement Fusion (ICF)
  13. Structure Analysis of High Current DC Disconnector Used in ITER Poloidal Field Converter
  14. Determination of Average Ion Temperature of the TVD Tokamak by a Simple Charge Exchange Analyzer Detector
  15. Application of High Energy Protons in Inertial Confinement Fusion by Using the Fast Ignitor Concept for DT Fusion
  16. Numerical Evaluation on Heat Shock Resistance of Two ITER-Like First Wall Mockups
  17. The Plasma Liner Compression Experiment
  18. Spheromak Formation and Current Sustainment Using a Repetitively Pulsed Source
  19. Erratum to: Kilotesla Magnetic Assisted Fast Laser Ignited Boron-11 Hydrogen Fusion with Nonlinear Force Driven Ultrahigh Accelerated Plasma Blocks
  20. Plasma Magnetic Fluctuations Measurement on the Outer Surface of IR-T1 Tokamak
  21. Stability of Plasma Configurations During Compression
  22. Investigation on the Neutronic Performance of a Fusion Reactor Using Flibe with Heavy Metal Fluorides
  23. Calculation of Beam Extraction Pulse Duration for Beam Angular Divergence Measurement of EAST Neutral Beam Injection
  24. Electrical Parameter Measurement System of the Ion Source for EAST Neutral Beam Injector
  25. Magnetohydrodynamic Free Convective Flow Past an Infinite Vertical Porous Plate with Magnetic Induction
  26. Activation Analysis and Comparison of Bio-shield Under ITER and ASP Neutron Irradiation

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