Paper Search Console

Home Search Page About Contact

Journal Title

Title of Journal: J Polym Res

Search In Journal Title:

Abbravation: Journal of Polymer Research

Search In Journal Abbravation:

Publisher

Springer Netherlands

Search In Publisher:

DOI

10.1007/s10565-006-0171-4

Search In DOI:

ISSN

1572-8935

Search In ISSN:
Search In Title Of Papers:

Dynamic stress relaxation behavior of nanogel fill

Authors: Suman Mitra Santanu Chattopadhyay Anil K Bhowmick
Publish Date: 2010/04/28
Volume: 18, Issue: 4, Pages: 489-497
PDF Link

Abstract

Longtime stress relaxation behavior of virgin elastomers chemically crosslinked nanogels and nanogel filled elastomers was studied with the help of a dynamic mechanical analyzer Sulfur crosslinked natural rubber and styrene butadiene rubber nanogels and nanocomposite gels were prepared and characterized using different methods These gels were added in to the virgin elastomer matrix at different concentrations Presence of crosslinked gels in elastomer matrix greatly influenced its stress relaxation behavior The effect of draw ratio gel loading and temperature on the stress relaxation behavior of elastomers was investigated in detail It was found that virgin elastomers displayed extremely longterm relaxation processes and the time required to achieve equilibrium dramatically decreased with the increase in crosslink density in the case of gels Timetemperature superposition studies revealed that stress relaxation process was accelerated and relaxation time reduced with a rise in temperature Finally experimental stress relaxation data were fitted with the empirical Chasset and Thirion equation with good agreement From the fitting parameters the characteristic relaxation time and the material parameter were estimated in order to understand the mechanism of the relaxation processes in the gels and the gel filled elastomersThe authors would like to thank Mr Kamal Hussain of Dept of Physics IIT Kharagpur for his help in curve fitting Suman Mitra gratefully acknowledges the financial assistance provided by the Council of Scientific and Industrial Research CSIR India Award No 9/81715/08EMRI dated 23102008

Keywords:

References

.
Search In Abstract Of Papers:
Other Papers In This Journal:
  1. Temperature-pH dual responsive OPGMA based copolymeric hydrogels prepared by gamma radiation: an optimisation study
  2. Synthesis and electrochromic performance of a novel polymer based on an oxidative polymer derived from carbazole and thiophene
  3. Thermo- and pH-sensitive interpenetrating poly(N-isopropylacrylamide)/carboxymethyl pullulan network for drug delivery
  4. High moisture strength of cassava starch/polyvinyl alcohol-compatible blends for the packaging and agricultural sectors
  5. Effects of phenyl-s-triazine moieties on thermal stability and degradation behavior of aromatic polyether sulfones
  6. Synthesis and characterization of thermo-insensitive, water-soluble associative polymers with good thickening properties at low and high temperatures
  7. Synthesis and application of polyurethane basic organic-inorganic hybrid materials as highly hydrophobic coatings
  8. Ammonia gas-sensing based on polythiophene film prepared through electrophoretic deposition method
  9. Synthesis and characterization of polyvinyl alcohol based semi interpenetrating polymeric networks
  10. Preparation and characterization of novel polyimide films containing amide groups
  11. A new thin film composite nanofiltration membrane based on PET nanofiber support and polyamide top layer: preparation and characterization
  12. Oxygen depletion properties of glucose-grafted polyethylene resins filled with sodium ascorbate/modified iron compounds
  13. Preparation and characterization of hemp hurd powder filled SBR and EPDM elastomers
  14. Synthesis of novel biodegradable material poly(lactic acid-trimesic acid) via direct melt copolycondensation and its characterization
  15. Toughening biodegradable polylactide with nanopores
  16. Synthesis of biodegradable material poly(lactic acid- co -sorbitol) via direct melt polycondensation and its reaction mechanism
  17. Fabrication of covalently-bonded polystyrene/SiO 2 composites by Pickering emulsion polymerization
  18. Synthesis of urea-formaldehyde resin by melt condensation polymerization
  19. Properties of a Calcium Phosphate Cement Synergistically Reinforced by Chitosan Fiber and Gelatin
  20. Synthesis and characterization of pH switching electrical conducting biopolymer hybrids for sensor applications
  21. Tailor-made polymer beads for gallic acid recognition and separation
  22. A novel approach to study the isothermal and non-isothermal crystallization kinetics of Poly(Ethylene Terephthalate) by Raman spectroscopy
  23. Characterization and preparation of poly(vinylidene fluoride) (PVDF) microporous membranes with interconnected bicontinuous structures via non-solvent induced phase separation (NIPS)
  24. Collagen-g-poly(Sodium Acrylate-co-Acrylamide)/sodium montmorillonite superabsorbent nanocomposites: synthesis and swelling behavior
  25. Synthesis of poly(ethylene glycol-b-styrene) block copolymers by reverse atom transfer radical polymerization
  26. Influence of graphene on thermal degradation and crystallization kinetics behaviour of poly(lactic acid)
  27. Electrochemical synthesis and characterization of poly(aniline-co-1-amino-9,10-anthraquinone), a nanosized conducting copolymer
  28. A novel method for synthesis of polypyrrole grafted chitin
  29. Biological and thermal investigations of polychelates derived from a novel terpolymer ligand
  30. Mixed micellar nanoparticles based on PCL-PEG-PPO-PEG-PCL pentablocks
  31. Surface behavior and micelle morphology of novel nonionic polyurethane bolaform amphiphilic block copolymers
  32. Organosoluble, Low-Colored Fluorinated Polyimides Based on 1,1-Bis[4-(4-amino-2-trifluoromethylphenoxy)phenyl]-1-phenyl-2,2,2-trifluoroethane
  33. Amine-terminated aromatic and semi-aromatic hyperbranched polyamides: synthesis and characterization
  34. Synthesis of a bismaleimide/cyanate ester copolymer containing phenolphthalein functional group with excellent dielectric properties and thermally stable
  35. Effect of amino acid-functionalization on the interfacial adhesion and behavior of multi-walled carbon nanotubes/poly(amide-imide) nanocomposites containing thiazole side unit
  36. Preparation, kinetics and microstructures of well-defined PS-b-PS/Bd diblock copolymers via RAFT miniemulsion polymerization
  37. Preparation, kinetics and microstructures of well-defined PS-b-PS/Bd diblock copolymers via RAFT miniemulsion polymerization
  38. One-step synthesis of poly(triazole-ether-quinoxaline)s using click reaction: preparation and properties of magnetic nanocomposites with modified Fe 3 O 4 for metal ions removal
  39. Effectiveness of a maleated compatibilizer on the tensile and tear properties of peroxide-cured metallocene polyethylene/clay nanocomposites
  40. The investigation on states of water in different hydrophilic polymers by DSC and FTIR
  41. Nonisothermal crystallization kinetics of PA6 and PA6/SEBS-g-MA blends
  42. Effect of synthesis variables on the fluorescence properties of CdSe-polystyrene latexes
  43. In situ chemical oxidative graft polymerization of thiophene derivatives from multi-walled carbon nanotubes
  44. Electrochemical deposition and characterization of polyaniline-graphene nanocomposite films and its corrosion protection properties
  45. A novel ternary copolymerized polyzwitterionic of poly (AM/DMAM/MAEDAPS): synthesis and solution properties
  46. Study on modifying the compression set of plasticized poly (vinyl chloride) by epoxy resin and post-heat treatment
  47. Study on ester-amide exchange reactions between Nylon 1010 and Ethylene-vinyl acetate rubber with different metal derivatives
  48. Effects of introducing bamboo charcoal on thermo-physical properties and combustion behavior of poly(ethylene terephthalate)
  49. Aggregation behavior of poly(methacrylic acid) with cucurbit[7]uril and the effect of ammonia ions on aggregation
  50. Novel homo- and co-poly(p-phenyene ether sulfone benzimidazole/sulfide sulfone benzimidazole)s: synthesis and properties
  51. Synthesis and characterization of aryl boron-containing thermoplastic phenolic resin with high thermal decomposition temperature and char yield
  52. The influence of molecular weight on the properties of polyacetal/hydroxyapatite nanocomposites. Part 2. In vitro assessment
  53. Phase separation behavior and fluorescence properties of poly( N -isopropylacrylamide) with chalcone side groups in mixed solvents
  54. A facile synthesis of hydrophilic glycopolymers with the ether linkages throughout the main chains
  55. Electrospinning short polymer micro-fibres with average aspect ratios in the range of 10–200
Search Result: