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Title of Journal: J Struct Chem

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Abbravation: Journal of Structural Chemistry

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SP MAIK Nauka/Interperiodica

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DOI

10.1016/0040-1625(73)90019-x

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ISSN

1573-8779

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Structural characterization of dichloridobisEmph

Authors: M R Malik S Ali M Fettouhi A A Isab S Ahmad
Publish Date: 2010/11/19
Volume: 51, Issue: 5, Pages: 976-979
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Abstract

A cadmiumII complex dichloridobisNN’dimethylthioureaScadmiumII CdDmtu2Cl2 1 was prepared and its structure was determined by Xray crystal structure analysis The cadmiumII ion is fourcoordinated and the complex has a distorted tetrahedral geometry The bond angles are in the range of 108183–110452° The metal ion is bonded to two chloride ions and two dimethylthiourea molecules through the sulfur atoms The crystal structure shows both intra and intermolecular hydrogen bonds The new complex was also characterized by IR and NMR spectroscopy and the spectroscopic data are discussed in terms of the nature of bonding


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Other Papers In This Journal:

  1. Inverse problem in XANES theory
  2. Crystal structure and fluorescence of a new 2D layered cadmium(II) malate coordination polymer
  3. Crystal structure of ammonium pentachloroaquaruthenate(III) (NH 4 ) 2 [Ru(H 2 O)Cl 5 ]
  4. Structure of the surface layer of mercury and adhesion of Langmuir monolayers on it
  5. Microwave spectrum, centrifugal perturbation, dipole moment, and conformation of 5-methyl-1,3-dioxane
  6. Structural thermodynamic characteristics and intermolecular interactions in aqueous solutions of hexamethylphosphorotriamide
  7. Crystal And Molecular Structure of Zinc DI-(4-Chlorphenylthioacetate) Dihydrate
  8. Crystal structure of a two-dimensional Co(II) coordination polymer: [Co(μ-PP) 2 (SCN) 2 ] n [PP = 2-(pyridine-3-yloxy)pyrazine]
  9. Method for evaluating the probability of structural isomer-isomer transformations with large numbers of quasidegenerations of the energy levels of the interactant subsystems
  10. Refinement of LiFe 5 O 8 crystal structure
  11. Theoretical study of the conformational structure and thermodynamic properties of 5-(4-oxo-1,3-thiazolidine-2-ylidene)-rhodanine and ethyl-5-(4-oxo-1,3-thiazolidine-2-ylidene)-rhodanine-3-acetic acid as acceptor groups of indoline dyes
  12. Crystal Structure of Iridium(III) trans -Trifluoroacetylacetonate
  13. Study of the properties and structure of nanosize membranes for acousto-optic devices
  14. Micellar synthesis and characterization of ultradispersed powders of ammonium nitrate
  15. Ab initio quantum-chemical study of the mechanism of methoxide ion formation in MOH/DMSO/CH 3 OH systems (M = Li, Na, K)
  16. The product of thermobaric treatment of Pt 0.25 Os 0.75

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