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Title of Journal: J Cent South Univ

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Abbravation: Journal of Central South University

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Central South University

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DOI

10.1007/bf02257529

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2227-5223

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Thermodynamic equilibrium diagram of CaClSubscrip

Authors: Weiping Liu Hui Xu Xiyun Yang Xichang Shi Ya Chen
Publish Date: 2012/10/04
Volume: 19, Issue: 10, Pages: 2751-2754
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Abstract

The lg cpH diagram of the CaCl2CaOH2H2O system and its two subsystems at 29815 K are constructed according to the theory of thermodynamic equilibrium The interaction characteristics between the solubility of CaCl2 and CaOH2 can be found out from the diagrams CaCl2ยท6H2O s CaOH2s and solution coexist when the pH value of solution is about 108 CaCl2 with the minimum solubility of 1 6824 g/L is in equilibrium with solution when the pH value is lower than 94 and CaOH2 with the minimum solubility of 2749 g/L is in equilibrium with solution at the pH value over 121 which provides a theoretical basis for the treatment and reuse of calcium chloride mother liquor for collocating lime cream which is the precipitant in the process of synthesizing magnesium hydroxide

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