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Title of Journal: Miner Petrol

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Abbravation: Mineralogy and Petrology

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Springer Vienna

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DOI

10.1002/hed.20661

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1438-1168

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Ferich Libearing magnesionigerite6Emphasis Typ

Authors: Zhuming Yang Kuishou Ding Jeffrey de Fourestier Qian Mao He Li
Publish Date: 2012/12/05
Volume: 107, Issue: 2, Pages: 163-169
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Abstract

The Ferich Libearing magnesionigerite6N6S occurs in the Xianghualing tinpolymetallic ore field Linwu County Hunan Province Peoples Republic of China It was found near the outer contact zone of the Laizhiling granite body and in the MiddleUpper Devonian carbonate rocks of Qiziqiao Formation The mineral formed during the skarn stage Its empirical formula is Sn181Li067Fe143Zn119 Mn041Σ303Al1489Mg146 Ti011Si001Σ1647O30OH2 The structure for magnesionigerite6N6S was solved and refined in space group R3 m with a = 571448 c = 5544611 Å V = 156804 Å3 to R1 = 00528 Based on the structural refinement of single crystal diffraction data the formula of magnesionigerite6N6S is Sn180Li097Fe189Zn091 Σ280 Al1460Mg163 Ti020Σ1643O30OH2 with Z = 3 Ferich Libearing magnesionigerite6N6S contains 074 wt Li2O The idealized chargebalanced composition of magnesionigerite6N6S may be expressed by bivalent and trivalent cations Mg2+4Al3+18O30OH2 The simplified general formula for the 6N6S polysomes in the nigerite and högbomite groups can be given as A x B18x O30OH2 x = ~4 where A = Mg2+ Fe2+ Zn2+ B = Al3+ Sn4+ Ti4+ Li+ □One of the authors Zhuming Yang is particularly grateful to Prof Dr Josef Zemann for his kind help and friendship during the past twenty years Best wishes on the occasion of his 90th birthday The authors acknowledge the help of Dr Hao Xiang for singlecrystal structure data collecting and Dr Tang Guoqiang for the SIMS analyses They would also like to thank the editor and the referees for their constructive comments The project was supported by the National Natural Science Foundation of China No 41272063


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