Journal Title
Title of Journal: Struct Chem
|
Abbravation: Structural Chemistry
|
Publisher
Kluwer Academic Publishers-Plenum Publishers
|
|
|
|
|
|
Authors: KiYoung Choi SunYoung Park YongMan Jeon Haiil Ryu
Publish Date: 2005/11/15
Volume: 16, Issue: 6, Pages: 649-656
Abstract
Tetradentate Schiffbase carboxylatecontaining ligands bis2pyridylmethylamino5valeric acid Hpmva and bis2pyridylmethylamino6caproic acid Hpmca react with copperII perchlorate to give rise to the carboxylated bridged chain complexes CuμpmvaH2OClO4 n 1 and CuμpmcaH2OClO4 n 2 These complexes have been characterized by Xray crystallography spectroscopic and variabletemperature magnetic susceptibility measurements In 1 and 2 each of the copperII ions exhibit CuN3O2 coordination environments with the three nitrogen atoms of the ligand and one oxygen atom belonging to the carboxylate group of an adjacent molecule occupying the basal position and a water molecule coordinated in the axial position The electronic spectra of the complexes are significantly affected by the coordination geometry Magnetic susceptibility measurements indicate that complexes exhibit very weak ferromagnetic interactions
Keywords:
.
|
Other Papers In This Journal:
- Inverse problem in XANES theory
- Crystal structure and fluorescence of a new 2D layered cadmium(II) malate coordination polymer
- Preface
- Crystal structure of ammonium pentachloroaquaruthenate(III) (NH 4 ) 2 [Ru(H 2 O)Cl 5 ]
- Crystal structure, IR-LD spectroscopic, theoretical and vibrational analysis of valinamide ester amide of squaric acid diethyl ester
- Conformational composition of meta - and ortho -fluoro(trifluoromethoxy)benzene as studied by vibrational spectroscopy
- Structure of the surface layer of mercury and adhesion of Langmuir monolayers on it
- Microwave spectrum, centrifugal perturbation, dipole moment, and conformation of 5-methyl-1,3-dioxane
- Tryptammonium (2 S ,3 S )-hydrogentartrate monohydrate [Struct Chem (2008) 19:147–154]: redetermination at 110 K and re-refinement against room temperature data
- Structural aspects of some organoselenium compounds
- Diastereoselective reaction of 1,3-dihydroxy calixarene with acylisocyanates: new and easy approach for preparing inherently chiral calyx[4]arenes
- An examination of the vaporization enthalpies and vapor pressures of pyrazine, pyrimidine, pyridazine, and 1,3,5-triazine
- Structural thermodynamic characteristics and intermolecular interactions in aqueous solutions of hexamethylphosphorotriamide
- What is a chemical substance and how is it formed?
- Crystal And Molecular Structure of Zinc DI-(4-Chlorphenylthioacetate) Dihydrate
- Structural analysis and biomedical potential of novel salicyloyloxy estrane derivatives synthesized by microwave irradiation
- Experimental and theoretical evidence suggests carbamate intermediates play a key role in CO 2 sequestration catalysed by sterically hindered amines
- 3D comparative structural study of 6-hydroxy-4-methyl-5,7-dinitrocoumarin using experimental and theoretical approaches
- Computational studies on tetrazole derivatives as potential high energy materials
- Crystal structure of a two-dimensional Co(II) coordination polymer: [Co(μ-PP) 2 (SCN) 2 ] n [PP = 2-(pyridine-3-yloxy)pyrazine]
- Synthesis, X-ray crystallography characterization, vibrational spectroscopy, and DFT theoretical studies of a new organic–inorganic hybrid material
- Method for evaluating the probability of structural isomer-isomer transformations with large numbers of quasidegenerations of the energy levels of the interactant subsystems
- Electronic properties of thienylene vinylene oligomers: synthesis and theoretical study
- Equilibrium structure and spectroscopic constants of maleic anhydride
- Structural characterization of dichloridobis( N,N’ -dimethylthiourea- S )cadmium(II)
- Theoretical studies on the proton-transfer reactions in propylene and pentadiene derivatives
- Anticancer drug IUdR and other 5-halogen derivatives of 2′-deoxyuridine: conformers, hydrates, and structure–activity relationships
- Paradigms and paradoxes: the aromaticity of 6:6 fused carbocycles and heterocycles as an extension of a study of indane and indene derivatives
- Refinement of LiFe 5 O 8 crystal structure
- Geometrical and energetical aspects of structure of 3,6-di- tert -butyl- o- benzoquinones
- Computational DFT studies on a series of toluene derivatives as potential high energy density compounds
- Cyclosulfurization of C 60 and C 70 fullerenes: a DFT study
- The annular tautomerism of imidazoles and pyrazoles: The possible existence of nonaromatic forms
- Mutual enhancing effects of the σ-hole interactions and halogen/hydrogen-bonded interactions in the iodine-ylide containing complexes
- Theoretical study of the conformational structure and thermodynamic properties of 5-(4-oxo-1,3-thiazolidine-2-ylidene)-rhodanine and ethyl-5-(4-oxo-1,3-thiazolidine-2-ylidene)-rhodanine-3-acetic acid as acceptor groups of indoline dyes
- Crystal Structure of Iridium(III) trans -Trifluoroacetylacetonate
- DFT study of α-maltose: influence of hydroxyl orientations on the glycosidic bond
- Study of the properties and structure of nanosize membranes for acousto-optic devices
- Crystal structure of three solvated Alpinumisoflavones
- Lanthanide contraction effect on the crystal structures of 2D lanthanide coordination polymers based on 2-(trifluoromethyl)-1 H -imidazole-4,5-dicarboxylic acid
- In silico modeling of functionalized graphene oxide-metal cluster conjugates as Raman probe: Raman activity of pyridine
- Chemistry, commentary and community: Discussion of “The NaDyBr 4 complex: its molecular structure and thermodynamic properties” by Varga and Hargittai
- Micellar synthesis and characterization of ultradispersed powders of ammonium nitrate
- Ab initio quantum-chemical study of the mechanism of methoxide ion formation in MOH/DMSO/CH 3 OH systems (M = Li, Na, K)
- The product of thermobaric treatment of Pt 0.25 Os 0.75
- ZnO porous structures synthesized by CTAB-assisted hydrothermal process
- A molecule on the surface or inside a spherical nanoparticle: the computation of the interaction energy in terms of the dielectric continuum model
- Does dehydrocyclization of 4-benzoylthiosemicarbazides in acetic acid lead to s -triazoles or thiadiazoles?
- Interplay of thermochemistry and Structural Chemistry , the journal (volume 17, 2006) and the discipline
- Syntheses and crystal structures of triorganotin(IV) complexes based on mixed ligands of 2,4,5-trifluoro-3-methoxybenzoic acid and 4,4′-bipy
- Restoring rotational invariance of Löwdin populations
- Density functional theory study of the regio‐ and stereoselectivity of 1,3-dipolar cycloaddition reactions between 2-ethylthio-4-phenyl-1-azetin and some substituted nitrile oxides
- Molecular structure and conformational properties of N -cyclohexylpiperidine as studied by gas-phase electron diffraction, mass spectrometry, IR spectroscopy and quantum chemical calculations
|