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Title of Journal: Macromol Res

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Abbravation: Macromolecular Research

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Publisher

The Polymer Society of Korea

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DOI

10.1007/s11626-014-9849-8

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ISSN

2092-7673

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Selforganization of amphiphilic diblock rodcoil

Authors: Keli Zhong Chunchang Yang Tie Chen Bingzhu Yin Long Yi Jin Zhegang Huang Eunji Lee
Publish Date: 2010/03/21
Volume: 18, Issue: 3, Pages: 289-296
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Abstract

An aromatic amphiphilic molecule consisting of three biphenyl groups and one styrene unit linked together with ether bonds as a rigid rod segment and polyethylene oxide with 17 repeating units as a coil segment was synthesized and its selfassembly behavior in the bulk state and aqueous solution was examined by DSC Xray scattering DLS and TEM This molecule based on a rod building block selfassembles into lamellar or hexagonal perforated layer HPL structures in the crystalline phase or liquid crystalline mesophase In an aqueous medium the molecule selfassembles into cylindrical aggregates and can be used as a supramolecular reactor for the Suzuki coupling reaction

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