Authors: Mehdi RahimiNasrabadi Bozorgmehr Maddah Mojtaba Shamsipur Abolghasem Moghimi
Publish Date: 2014/09/16
Volume: 43, Issue: 11, Pages: 1873-1885
Abstract
The kinetics of the complexation reactions of Ba2+ and Sr2+ in AN and 955 wt ANDMF were studied and the kinetic parameters for the decomplexation step E a ΔH ΔS and ΔG were determined in the temperature range of 17–47 °C Kinetic parameters reveal that both dissociative and biomolecular mechanisms contribute to the exchange of the 30C10 complexes Furthermore the 30C10·Ba2+ complex was synthesized and its crystal structure was determined through single crystal Xray analysis
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