Authors: Artem M Mishchenko Elena K Trunova Alexandra S Berezhnytska
Publish Date: 2015/10/20
Volume: 44, Issue: 11, Pages: 2117-2128
Abstract
The equilibrium between unsaturated beta ketoester allyl acetoacetate and certain lanthanide ions La3+ Pr3+ Nd3+ Sm3+ Gd3+ Ho3+ Er3+ Tm3+ Yb3+ Lu3+ was studied in mixed dioxane–water–ethyl acetate media The formation of cationic 11 and 12 type complexes was shown and their formation constants were determined by potentiometric titration For the 12 type complexes a molecular mechanics geometry optimization was performed and the bonding parameters were calculated on the basis of their electronic absorption spectra using the lanthanide aquaions as reference standards The correlation between the nephelauxetic ratio and the relative metal–ligand bond length shortening due to the complexation was revealed and clarified
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