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Title of Journal: Int J Thermophys

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Abbravation: International Journal of Thermophysics

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Kluwer Academic Publishers-Plenum Publishers

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DOI

10.1016/0031-9422(90)80222-3

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1572-9567

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Conductometric Study of Some Metal Halides in Glyc

Authors: Mahendra Nath Roy Bhoj Bahadur Gurung Vikas Kumar Dakua
Publish Date: 2006/09/26
Volume: 27, Issue: 5, Pages: 1539-1550
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Abstract

Electrolytic conductivities of potassium halides KX X = Cl− Br− I− have been investigated in 10 20 and 30 mass glycerol + H2O mixtures at 2980 3080 and 3180 K The conductance data have been analyzed by the Fuossconductance–concentration equation in terms of the limiting molar conductance Λ0 the association constant K A and the distance of closest approach of ion R The association constant K A tends to increase in the order 10 mass   20 mass   30 mass glycerol + water mixtures while it decreases with temperature Thermodynamic parameters ΔH 0 ΔG 0 and ΔS 0 are obtained and discussed Also Walden products Λ0η are reported The results have been interpreted in terms of ion–solvent interactions and structural changes in the mixed solvents

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