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Title of Journal: J Clust Sci

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Abbravation: Journal of Cluster Science

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Springer US

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DOI

10.1007/bf02548540

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ISSN

1572-8862

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The Reactions of Two New Alkoxysilyl Functionaliz

Authors: Aldo Arrais Enrico Sappa Andrea Secco
Publish Date: 2007/05/22
Volume: 18, Issue: 3, Pages: 535-548
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Abstract

The new alkoxysilylfunctionalized alkynes HC≡CCH2NHC=ONHCH23SiOEt3 and HC≡CC6H4–NHC=ONHCH23SiOEt3 have been synthesized using literature methods These have been reacted with Fe3CO12 Ru3CO12 and Co2CO8 With the iron carbonyl only decomposition was observed with Ru3CO12 splitting of the alkynes into their parent components and formation of the complexes μHRu3CO9HC=NCH23SiOEt3 μHRu3CO9C–CC6H4NH2 and μH2Ru3CO9HC–CCH3 occurred Finally with Co2CO8 formation of complexes Co2CO6HC2R R=C6H4NH2 CH2NHCONHCH23SiOEt3 C6H4NHCONHCH23SiOEt3 containing the intact alkynes could be obtained

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  2. Molybdenum Bisphosphonates with Cr(III) or Mn(III) Ions
  3. Novel Nanomaterials Based on Inorganic Molybdenum Octahedral Clusters
  4. Computer Simulation of Binary Platinum–Cobalt Nanoclusters Interaction with Oxygen
  5. A New Sandwich Polyoxometalate Constructed from a Zn 6 12+ Hexagon Cluster Sandwiched by Two B-α-[BiW 9 O 33 ] 9−
  6. Synthesis and Characterization of Stable Iron Oxide Nanoparticle with Amino Covalent Binding on the Surface for Biomedical Application
  7. Reactions of Unsaturated Quinoline Triosmium Clusters [Os 3 (CO) 9 (μ 3 -η 2 -C 9 H 5 (4-R)N)(μ-H)] (R=Me or H) with Tetramethylthiourea: X-ray Structures of [Os 3 (CO) 8 (μ-η 2 -C 9 H 5 (4-Me)N)(η 2 -SC(NMe 2 NCH 2 Me)(μ-H) 2 ] and [Os 3 (CO) 9 (μ-η 2 -C 9 H 6 N)(η 1 -SC(NMe 2 ) 2 )(μ-H)]
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  11. Synthesis and Characterization of a 3-D Framework Constructed from [V 12 B 18 O 54 (OH) 6 (H 2 O)] 10− Clusters and K + Cations
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