Journal Title
Title of Journal: J Clust Sci
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Abbravation: Journal of Cluster Science
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Authors: Antoine Bonnot Carsten Strohmann Michael Knorr Pierre D Harvey
Publish Date: 2013/10/08
Volume: 25, Issue: 1, Pages: 261-275
Abstract
The CuX salts X = Br I react with 14biscyclohexylthiobutane L2 in a 11 ratio to form the corresponding isostructural and weakly luminescent 1D coordination polymers Cu2X2μL22 n X = Br 4 X = I 3 as determined by Xray crystallography The previously reported reaction of CuI with 14bisphenylthiobutane L1 in a 21 metaltoligand ratio provides a 2D polymer Cu4I4μL12 n 1 Knorr et al Dalton Trans 38948–955 2009 where the Cu4I4 unit exhibits the common cubane structure and an intense luminescence centered at 555 and 565 nm respectively at 298 and 77 K When CuI reacts with L2 in a 21 metaltoligand ratio a new material 2 is formed but no Xray structure was obtained The intense and characteristic luminescence of polymer 2 is strongly indicative of the formation of the cubane Cu4I4 unit The new materials have been characterized by solidstate UV–Vis rasingangle transmittance spectroscopy luminescence spectroscopy and emission lifetime measurementsThis research was supported by the CNRS the Natural Sciences and Engineering Research Council of Canada NSERC le Fonds Québécois de la Recherche sur la Nature et les Technologies FQRNT and the Centre d’Etudes des Matériaux Optiques et Photoniques de l’Université de Sherbrooke CEMOPUS
Keywords:
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Other Papers In This Journal:
- Reactivity of Alkyne-Substituted Transition Metal Clusters: An Overview
- Molybdenum Bisphosphonates with Cr(III) or Mn(III) Ions
- Novel Nanomaterials Based on Inorganic Molybdenum Octahedral Clusters
- Computer Simulation of Binary Platinum–Cobalt Nanoclusters Interaction with Oxygen
- A New Sandwich Polyoxometalate Constructed from a Zn 6 12+ Hexagon Cluster Sandwiched by Two B-α-[BiW 9 O 33 ] 9−
- Synthesis and Characterization of Stable Iron Oxide Nanoparticle with Amino Covalent Binding on the Surface for Biomedical Application
- Reactions of Unsaturated Quinoline Triosmium Clusters [Os 3 (CO) 9 (μ 3 -η 2 -C 9 H 5 (4-R)N)(μ-H)] (R=Me or H) with Tetramethylthiourea: X-ray Structures of [Os 3 (CO) 8 (μ-η 2 -C 9 H 5 (4-Me)N)(η 2 -SC(NMe 2 NCH 2 Me)(μ-H) 2 ] and [Os 3 (CO) 9 (μ-η 2 -C 9 H 6 N)(η 1 -SC(NMe 2 ) 2 )(μ-H)]
- Introducing Transition-Metal Complex Together with Conjugated Ligand into Polymeric Iodoplumbate: Structure Characterization, Properties and Theoretical Study of a New Semi-Conductive Hybrid: {[Cu(II)(2,2′-bipy) 3 ][Pb 2 I 6 ]} n
- Synthesis of Platinum Nanoparticles-Decorated Poly( p -Phenylenediamine) Colloids with a High Performance for Methanol Electrocatalysis for Direct Methanol Fuel Cells
- Low-Energy Structures of Binary Pt–Sn Clusters from Global Search Using Genetic Algorithm and Density Functional Theory
- Synthesis and Characterization of a 3-D Framework Constructed from [V 12 B 18 O 54 (OH) 6 (H 2 O)] 10− Clusters and K + Cations
- Structural, Electronic, and Magnetic Properties of MB n (M = Y, Zr, Nb, Mo, Tc, Ru, n ≤ 8) Clusters
- Small Tin Oxide Grains: Structural and Electronic Properties Evaluated using the Density Functional Theory
- One Novel Trinuclear Nickel(II) Cluster Containing a Pyramidal Ni 3 ( μ 3 -OH) Core: Crystal Structure and Hirshfeld Surface Analysis
- Mosquitocidal, Antimalarial and Antidiabetic Potential of Musa paradisiaca -Synthesized Silver Nanoparticles: In Vivo and In Vitro Approaches
- Properties of Au/ZnO Nanocomposite Prepared by Laser Irradiation of the Mixture of Individual Colloids
- Properties of Au/ZnO Nanocomposite Prepared by Laser Irradiation of the Mixture of Individual Colloids
- Foreword
- Bio-template Synthesis of Nanoparticle by Cage-shaped Protein Supramolecule, Apoferritin
- Au Nanoparticles Supported Nanoporous ZnO Sphere for Enhanced Photocatalytic Activity Under UV-Light Irradiation
- One-Dimensional Bi 2 WO 6 Nanofibers Controllable Synthesis by Electrospinning and Enhanced Visible Photocatalytic Degradation Performances
- New Member of Organic Ligand Functionalized TMSP: Synthesis, Characterized and Properties of Na 15 [(Mn II (COOH)) 3 (AsW 9 O 33 ) 2 ]·15H 2 O
- Facile Synthesis of ZIF-8/ZnO/Polyoxometalate Ternary Composite Materials for Efficient and Rapid Removal of Cationic Organic Dye
- Investigation of the Thermal Properties of a Series of Copper Selenide Cluster Molecules
- The Reactions of Two New Alkoxy-silyl Functionalized Alkynes with M 3 (CO) 12 {M = Fe, Ru} and Co 2 (CO) 8 . Spectroscopic Identification of the Products
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