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Title of Journal: J Clust Sci

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Abbravation: Journal of Cluster Science

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Publisher

Springer US

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DOI

10.1007/bf02840598

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ISSN

1572-8862

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Introducing TransitionMetal Complex Together with

Authors: XiaoBo Chen HaoHong Li ZhiRong Chen JiBo Liu JunBo Li HaiJun Dong YanLing Wu
Publish Date: 2009/08/05
Volume: 20, Issue: 3, Pages: 611-620
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Abstract

A new hybrid coordination polymer CuII22′bipy3Pb2I6 n 1 was synthesized by the reaction of CuNO32 22′bipy PbI2 and NaI in DMF/DMSO mixed solvent As revealed by Xray structural analysis 1 consists of Pb2I6 n 2n− polyanions and discrete CuII22′bipy32+ structuredirecting agent cations The polymeric negative chain Pb2I6 n 2− is built up by facesharing of PbI6 octahedra Structuredirecting reagent cations and polymeric negative chains are in combination with each other by static attracting force to form socalled hybrid structure Experimental and theoretical optical property investigations indicate that 1 possesses semiconductor property DFT calculation was executed to probe the electronic structure of 1 To our interest when using both second metal and π system as electronic tuning species conjugated system is more preferable

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Other Papers In This Journal:
  1. Reactivity of Alkyne-Substituted Transition Metal Clusters: An Overview
  2. Molybdenum Bisphosphonates with Cr(III) or Mn(III) Ions
  3. Novel Nanomaterials Based on Inorganic Molybdenum Octahedral Clusters
  4. Computer Simulation of Binary Platinum–Cobalt Nanoclusters Interaction with Oxygen
  5. A New Sandwich Polyoxometalate Constructed from a Zn 6 12+ Hexagon Cluster Sandwiched by Two B-α-[BiW 9 O 33 ] 9−
  6. Synthesis and Characterization of Stable Iron Oxide Nanoparticle with Amino Covalent Binding on the Surface for Biomedical Application
  7. Reactions of Unsaturated Quinoline Triosmium Clusters [Os 3 (CO) 9 (μ 3 -η 2 -C 9 H 5 (4-R)N)(μ-H)] (R=Me or H) with Tetramethylthiourea: X-ray Structures of [Os 3 (CO) 8 (μ-η 2 -C 9 H 5 (4-Me)N)(η 2 -SC(NMe 2 NCH 2 Me)(μ-H) 2 ] and [Os 3 (CO) 9 (μ-η 2 -C 9 H 6 N)(η 1 -SC(NMe 2 ) 2 )(μ-H)]
  8. Synthesis of Platinum Nanoparticles-Decorated Poly( p -Phenylenediamine) Colloids with a High Performance for Methanol Electrocatalysis for Direct Methanol Fuel Cells
  9. Low-Energy Structures of Binary Pt–Sn Clusters from Global Search Using Genetic Algorithm and Density Functional Theory
  10. Synthesis and Characterization of a 3-D Framework Constructed from [V 12 B 18 O 54 (OH) 6 (H 2 O)] 10− Clusters and K + Cations
  11. Structural, Electronic, and Magnetic Properties of MB n (M = Y, Zr, Nb, Mo, Tc, Ru, n ≤ 8) Clusters
  12. Small Tin Oxide Grains: Structural and Electronic Properties Evaluated using the Density Functional Theory
  13. One Novel Trinuclear Nickel(II) Cluster Containing a Pyramidal Ni 3 ( μ 3 -OH) Core: Crystal Structure and Hirshfeld Surface Analysis
  14. Mosquitocidal, Antimalarial and Antidiabetic Potential of Musa paradisiaca -Synthesized Silver Nanoparticles: In Vivo and In Vitro Approaches
  15. Properties of Au/ZnO Nanocomposite Prepared by Laser Irradiation of the Mixture of Individual Colloids
  16. Properties of Au/ZnO Nanocomposite Prepared by Laser Irradiation of the Mixture of Individual Colloids
  17. Foreword
  18. Metal-to-Ligand Ratio Effect on the Size of Copper Iodide and Copper Bromide Clusters in 1,4-Bis(cyclohexylthio)butane-Spanned Coordination Polymers
  19. Bio-template Synthesis of Nanoparticle by Cage-shaped Protein Supramolecule, Apoferritin
  20. Au Nanoparticles Supported Nanoporous ZnO Sphere for Enhanced Photocatalytic Activity Under UV-Light Irradiation
  21. One-Dimensional Bi 2 WO 6 Nanofibers Controllable Synthesis by Electrospinning and Enhanced Visible Photocatalytic Degradation Performances
  22. New Member of Organic Ligand Functionalized TMSP: Synthesis, Characterized and Properties of Na 15 [(Mn II (COOH)) 3 (AsW 9 O 33 ) 2 ]·15H 2 O
  23. Facile Synthesis of ZIF-8/ZnO/Polyoxometalate Ternary Composite Materials for Efficient and Rapid Removal of Cationic Organic Dye
  24. Investigation of the Thermal Properties of a Series of Copper Selenide Cluster Molecules
  25. The Reactions of Two New Alkoxy-silyl Functionalized Alkynes with M 3 (CO) 12 {M = Fe, Ru} and Co 2 (CO) 8 . Spectroscopic Identification of the Products
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