Authors: Süleyman Köytepe M Hurşit Demirel Turgay Seçkin
Publish Date: 2013/06/27
Volume: 23, Issue: 5, Pages: 1104-1112
Abstract
A novel metallosupramolecular polytopic ligand was synthesized from the attachment reaction involving an amino groupfunctionalized multiwall carbon nanotube and 4chloro22′6′2″terpyridine used for the preparation of metallosupramolecular polymers with CoII or NiII ions Different colors were observed depending on either the ligands or the metal ions in this type of supramolecular assembly The created supramolecular polymers were characterized by means of structure morphology and stimuliresponsive performance employing scanning electron microscopy amperometric techniques UV–Vis and Fourier transform infrared spectroscopy UV–Vis spectroscopy and cyclic voltammetry studies confirmed that both the optical and electrochemical properties of metallosupramolecular materials are affected by the substituent at the pyridine periphery
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