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Title of Journal: J Inorg Organomet Polym

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Abbravation: Journal of Inorganic and Organometallic Polymers and Materials

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Springer US

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DOI

10.1016/0010-8804(94)90100-7

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ISSN

1574-1451

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MetalIIDirected Various PolyoxometalatesBased

Authors: XiuLi Wang DanNa Liu HongYan Lin Na Han GuoCheng Liu
Publish Date: 2014/12/17
Volume: 25, Issue: 4, Pages: 671-679
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Abstract

Three new polyoxometalates POMsbased hybrid compounds H6CuC5H5N22Mo8O27H2O2·2C5H6N2·2H2O 1 H6CoC5H5N22Mo8O27H2O2·2C5H6N2·2H2O 2 and H4C5H6N22NiOH6Mo6O18·4H2O 3 C5H6N2 = 3aminopyridine have been synthesized by selfassembly of NH46Mo7O24·4H2O C5H6N2 and different metal nitrates at different pH values The single crystal Xray diffraction IR spectra PXRD and thermogravimetric analyses have been used to characterize the title compounds Compounds 1 and 2 are isostructural 3D metal–organic frameworks with a CdSO4type topology which are constructed from infinite Mo8O27 6− inorganic chains in uncommon ABAB linking mode Compound 3 exhibits a 1D supramolecular chain derived from in situ formed Andersontype NiOH6Mo6O184− anions and 3aminopyridine via hydrogenbonding interactions The structural diversities indicate that metal ions show great effect on the construction of different POMs and final architectures The electrochemical behavior of compound 1 the photocatalytic activities of compounds 1–3 have been investigated in detailThis work was financially supported by the National Natural Science Foundation of China No 21171025 and 21471021 Program of New Century Excellent Talents in University NCET090853 and Program of Innovative Research Team in University of Liaoning Province LT2012020

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Other Papers In This Journal:
  1. New Organotin/CuCN/Quinazoline 3D-Supramolecular Coordination Polymers Having Catalytic and Luminescence Activities
  2. Photoluminescent Polymer Composites Based on New Tb(III) and Eu(III): Maleimide Complexes
  3. Synthesis, Morphology, and Viscoelastic Properties of Polyhedral Oligomeric Silsesquioxane Nanocomposites with Epoxy and Cyanate Ester Matrices
  4. Metal-Induced Structural Switching of a Folded Quinone-Sandwiched Porphyrin
  5. Sonochemical Synthesis of a New Lead(II) Coordination Polymer with 2-Quinoline Carboxylate Ligand: A Precursor for the Preparation of Nano-structured Lead(II) Oxide
  6. Sonochemical Synthesis of Two New Nano-structured Cadmium(II) Supramolecular Complexes
  7. Controllable Synthesis of NiSe 2 Nanostructures via Hydrothermal Process for Photocatalytic and Solar Cell Applications
  8. Co-sensitization Promoted Light Harvesting for Dye-Sensitized Solar Cells
  9. Synthesis, Characterization and Biological Studies of Oil Based Tin Polymer
  10. Synthesis and Characterization of Mn 3 O 4 /BC Nanocomposite and Its Antimicrobial Activity
  11. Synthesis, Structures and Properties of Novel Platinum(II) Acetylide Complexes and Polymers with Tri(tolyl)phosphine as the Auxiliary Ligand
  12. Gamma Radiation Synthesis and Characterization of Starch Based Polyelectrolyte Hydrogels Loaded Silver Nanoparticles
  13. Ionic Conductivity of Cross-linked Polymethacrylate Derivatives/Cyclophosphazenes/Li + Salt Complexes
  14. Preparation and Dielectric Properties of AGS@CuPc/PVDF Composites
  15. Synthesis and Characterization of Platinum Nanoparticles on PT-Coated Mesoporous Silica as an Electrocatalyst for Direct Methanol Fuel Cells
  16. Synthesis, Optical Properties, and Photoluminescence of Organometallic Acetylide Polymers of Platinum Functionalized with Si and Ge-Bridged Bis(3,6-Diethynyl-9-butylcarbazole)
  17. Optical Properties of Eu 3+ -Doped Aluminophosphate Glass with a High Concentration of Silver and Tin
  18. Synthesis of Metal-containing Polymers via Ring Opening Metathesis Polymerization (ROMP). Part II: Polymers Containing Transition Metals
  19. A Chemical Precipitation Method to Synthesize Na 3 CrF 6 Crystal with Unique Shapes
  20. One-Step Fabrication of Magnetic Carbon Nanocomposite as Adsorbent for Removal of Methylene Blue
  21. Quaternary Ammonium Salts (QAS) Modified Polysiloxane Biocide Supported on Silica Materials
  22. Historical Overview of the Army Contributions to Phosphazene Chemistry
  23. Phosphoryl Triamide Polymers Revisited: Identification of Structural Units with ESI-MS/MS and Solid State NMR
  24. Synthesis and Self-assembling Properties of 2,2′:6′,2″-Terpyridine-Based Carbon Nanotube Coordination Polymers
  25. Linear Coordination Polymers Assembled from Dinuclear Cu(I) Units: Interchain π–π and CH–π Interactions in Controlling Alignments of Polymeric Chains in Solid State
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  27. A novel Route to Synthesize p -Terphenyl from Benzene by the Catalysis of h-BN Nanoparticles
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