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Title of Journal: Polym Bull

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Abbravation: Polymer Bulletin

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Springer Berlin Heidelberg

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DOI

10.1016/j.agwat.2010.10.008

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ISSN

1436-2449

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Using Agrawal integral equation and thermogravimet

Authors: HuiWang Cui ShiaoWei Kuo
Publish Date: 2013/08/13
Volume: 70, Issue: 11, Pages: 3143-3153
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Abstract

In this study an exfoliated montmorillonite was prepared through click chemistry from a singly azidofunctionalized polyhedral oligomeric silsesquioxane derivative and a montmorillonite intercalated with propargyldimethylstearylammonium bromide This exfoliated montmorillonite was then introduced into a benzoxazine matrix—prepared from paraformaldehyde aniline and phenol—to form polymer/exfoliated clay nanocomposites Thermogravimetric analysis revealed that the pyrolysis kinetics had a close relationship with the structure of montmorillonite the assembly process the anchoring effect the compatibility of the polymer and intercalator and the char yield The polymer/exfoliated clay nanocomposites had a same mechanism function and the kinetic compensation effect equations revealed the pyrolysis essences

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