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Title of Journal: Catal Lett

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Abbravation: Catalysis Letters

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Springer US

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DOI

10.1007/bf02709091

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ISSN

1572-879X

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OxygenNonstoichiometric YBaCoSubscript4/Subscr

Authors: Outi Parkkima Ana SilvestreAlbero Joaquin SilvestreAlbero Maarit Karppinen
Publish Date: 2014/10/31
Volume: 145, Issue: 2, Pages: 576-582
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Abstract

Here we present oxygennonstoichiometric transition metal oxides as highly prominent candidates to catalyze the industrially important oxidation reactions of hydrocarbons when hydrogen peroxide is employed as an environmentally benign oxidant The proofofconcept data are revealed for the complex cobalt oxide YBaCo4O7+δ 0  δ  15 in the oxidation process of cyclohexene In the 2h reaction experiments YBaCo4O7+δ was found to be significantly more active 60  conversion than the commercial TiO2 catalyst 20  even though its surface area was less than one tenth of that of TiO2 In the 7h experiments with YBaCo4O7+δ 100  conversion of cyclohexene was achieved Immersion calorimetry measurements showed that the high catalytic activity may be ascribed to the exceptional ability of YBaCo4O7+δ to dissociate H2O2 and release active oxygen to the oxidation reaction

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Other Papers In This Journal:
  1. Synthesis and Catalytic Performance of ZSM-5/MCM-41 Zeolites With Varying Mesopore Size by Surfactant-Directed Recrystallization
  2. Enhanced Low-Temperature Activity of Ag-Promoted Co-ZSM-5 for the CH 4 -SCR of NO
  3. Hydrogenation of m -Dinitrobenzene Over Pt Supported Catalysts on TiO 2 –Al 2 O 3 Binary Oxides
  4. Synthesis of Two Novel Water-Soluble Iron Phthalocyanines and Their Application in Fast Chromogenic Identification of Phenolic Pollutants
  5. Metal Support Interactions in Co 3 O 4 /Al 2 O 3 Catalysts Prepared from w/o Microemulsions
  6. Effect of CeO 2 Doping on Structure and Catalytic Performance of Co 3 O 4 Catalyst for Low-Temperature CO Oxidation
  7. Application of Inelastic Neutron Scattering to the Methanol-to-Gasoline Reaction Over a ZSM-5 Catalyst
  8. Catalytic Method for N -Methyl-4-pyridone Synthesis in the Presence of ZnAl 2 O 4
  9. Oxidation of Olefins Using Rhenium Supported by Imidazole-Functionalized Amphiphilic Copolymers
  10. Radiochromatographic studies of isobutylene oxidation over SnO 2
  11. Effect of Enhanced Support Acidity on the Sulfate Storage and the Activity of Pt/γ-Al 2 O 3 for NO Oxidation and Propylene Oxidation
  12. Synthesis, Characterization and Catalytic Properties of Chiral BINOL Functionalized Mesoporous Silicas for Enantioselective Morita-Baylis-Hillman Reaction
  13. Effect of Mg Addition on the Physical and Catalytic Properties of Cu/CeO 2 for NO + CO Reduction
  14. Deep HDS of Diesel Fuel: Inhibiting Effect of Nitrogen Compounds on the Transformation of the Refractory 4,6-Dimethyldibenzothiophene Over a NiMoP/Al 2 O 3 Catalyst
  15. Mechanochemical Synthesis and Electrochemical Characterization of Nano Crystalline Calcium Ferrite
  16. Preparation, Characterization and Reactivity of Keggin Type Phosphomolybdates, H 3−2 x Ni x PMo 12 O 40 and (NH 4 ) 3−2 x Ni x PMo 12 O 40 , for Adipic Acid Synthesis
  17. Functionalized Poly(ethylene glycol)-Stabilized Palladium Nanoparticles as an Efficient Catalyst for Aerobic Oxidation of Alcohols in Supercritical Carbon Dioxide/Poly(ethylene glycol) Biphasic Solvent System
  18. Synthesis of CaIn 2 O 4 Rods and Its Photocatalytic Performance Under Visible-light Irradiation
  19. Glycerol hydrogenolysis to propylene glycol
  20. Glycothermal Synthesis and Catalytic Properties of Nanosized Zn 1− x Co x Al 2 O 4 ( x = 0, 0.5, 1.0) Spinels in Phenol Methylation
  21. Fe 3 O 4 Nanoparticles-Supported Palladium-Bipyridine Complex: Effective Catalyst for Suzuki Coupling Reaction
  22. Cluster Structure and Reactions: Gaining Insights into Catalytic Processes
  23. Hydrocracking and Hydroisomerization of n -Hexadecane, n -Octacosane and Fischer–Tropsch Wax Over a Pt/SiO 2 –Al 2 O 3 Catalyst
  24. Reduction of Ketones with Silanes Catalysed by a Cyclopentadienyl-Functionalised N -Heterocyclic Iron Complex
  25. The First Case of Competitive Heterogeneously Catalyzed Hydrogenation using Continuous-Flow Fixed-Bed Reactor System: Hydrogenation of Binary Mixtures of Activated Ketones on Pt-Alumina and on Pt-Alumina-Cinchonidine Catalysts
  26. Steam reforming of ethanol on Ni–CeO 2 –ZrO 2 catalysts: Effect of doping with copper, cobalt and calcium
  27. Different Catalytic Reactions of n -Hexane and 1-Hexene on Molybdenum Based Catalysts
  28. Palladium-Schiff Base Complex Immobilized Covalently on Magnetic Nanoparticles as an Efficient and Recyclable Catalyst for Heck and Suzuki Cross-Coupling Reactions
  29. From Gas to Liquid Phase Sulfidation: An IR Spectroscopy Study
  30. “An American Scientist: The Autobiography of Gabor A Somorjai with Mitch Jacoby”
  31. Low-Temperature CO Oxidation of Gold Catalysts Loaded on Mesoporous TiO 2 Whisker Derived from Potassium Dititanate
  32. Hydrogen Production by Steam Reforming of Liquefied Natural Gas over Mesoporous Ni-Al 2 O 3 Catalysts Prepared by a Co-Precipitation Method: Effect of Ni/Al Atomic Ratio
  33. Liquid-Phase Selective Hydrogenation of 1-Heptyne over Pd/TiO 2 Catalyst Synthesized by One-Step Flame Spray Pyrolysis
  34. Nanocatalysis I: Synthesis of Metal and Bimetallic Nanoparticles and Porous Oxides and Their Catalytic Reaction Studies
  35. Copper-Catalysed One-Pot Synthesis of 2,3,4,9-Tetrahydro-1 H -Xanthen-1-Ones from 2-Halobenzylbromides and Cyclic-1,3-Diketones in Water
  36. Selective hydrogenolysis of glycerol to propylene glycol on Cu–ZnO catalysts
  37. Reduction of N -(alkoxy(aryl)methyl)benzamide Compounds by a Hantzsch Ester 1,4-Dihydropyridine Using Pd/C as a Catalyst
  38. Role of Baria Dispersion in BaO/Al 2 O 3 Catalysts for Transesterification
  39. Peculiarities of dehydroaromatization of CH 4 –C 2 H 6 and CH 4 over Mo/ZSM-5 catalysts
  40. Properties and Catalytic Performance for Methane Combustion of LaMnO 3 Perovskite Prepared in Oil–Water Two-phase System
  41. Dealumination of Zeolite Beta Catalyst Under Controlled Conditions for Enhancing its Activity in Acylation and Esterification
  42. Preparation and catalytic activity of a new dioxomolybdenum(VI) complex for olefin epoxidation
  43. Preparation of La-Mn-O Perovskite Catalyst by Microwave Irradiation Method and its Application to Methane Combustion
  44. Low Temperature NO Storage of Zeolite Supported Pd for Low Temperature Diesel Engine Emission Control
  45. A Cu Nanoparticle Embedded in Electrospundoped Carbon Nanofibers as Efficient Catalysts for Ullmann O-Arylation of Aryl Halides with Various Phenols
  46. Activated Carbon Modified with Different Chemical Agents as a Catalyst in the Dehydration and Dehydrogenation of Isopropanol
  47. Nanostructured Cu-Doped Ceria Obtained by Reverse Microemulsion Method as Catalysts for Incineration of Selected VOCs
  48. A Fine Dispersed Cobalt Catalyst with Macro-Pore for Hydroformylation of 1-Hexene
  49. Dialkylation of Naphthalene with Isopropanol Over H 3 PO 4 /MCM-41 Catalysts for the Environmentally Friendly Synthesis of 2,6-Dialkylnaphthalene
  50. Synthesis, Characterization and Catalytic Application of MCM 41 Supported Phenanthrolinium Dibromide Catalyst for Aza-Michael Addition Reaction in Aqueous Medium
  51. Comparative Study of Rubidium and Cesium as Promoters in Carbon-supported Ruthenium Catalysts for Ammonia Synthesis
  52. Mesoporous SBA-15 with Short Mesochannels Immobilized Natural Quinine for Asymmetric Michael Addition of Chalcones
  53. First Report About the Use of Micellar Keggin Heteropolyacids as Catalysts in the Green Multicomponent Synthesis of Nifedipine Derivatives
  54. Oxidation of Saturated Hydrocarbons to Alkyl Hydroperoxides by a ‘H 2 O 2 /Titanosilicalite-1/NaOH/MeCN’ System
  55. Catalytic Oxidation of NO to NO 2 Over Co–Ce–Zr Solid Solutions: Enhanced Performance of Ce–Zr Solid Solution by Co
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