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Title of Journal: Russ Chem Bull

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Abbravation: Russian Chemical Bulletin

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Springer US

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DOI

10.1016/0005-2744(69)90395-7

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1573-9171

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Volume change on the formation of the complex EDTA

Authors: V D Kiselev E A Kashaeva I I Shakirova A I Konovalov
Publish Date: 2012/05/29
Volume: 60, Issue: 8, Pages: 1766-1768
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Abstract

The volume of the chelate formation between ethylenediaminetetraacetic acid tetrasodium salt and the Mg2+ cation in water was measured for the first time The volume of the complex formation increases with dilution of the solution and reaches the limit of 299±3 cm3 mol−1 at 25 °C The changes in the volume during the chelation and the entropy of the complex formation were compared

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