Authors: K N Gavrilov I V Chuchelkin S V Zheglov N N Groshkin I M Novikov E A Rastorguev V A Davankov
Publish Date: 2012/06/26
Volume: 60, Issue: 10, Pages: 2063-2067
Abstract
New PNbidentate diastereomeric amidophosphite ligands were obtained by phosphorylation of S2phenylaminomethylpyrrolidine involving 4S5S and 4R5R2chloro45diphenyl132dioxaphospholanes Their efficiency in the Pdcatalyzed enantioselective allylic substitution was compared it was found that the reaction involving E13diphenylallyl acetate and pyrrolidine gives up to 75 ee
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