Journal Title
Title of Journal: J Incl Phenom Macrocycl Chem
|
Abbravation: Journal of Inclusion Phenomena and Macrocyclic Chemistry
|
Publisher
Springer Netherlands
|
|
|
|
|
|
Authors: Maaouia Souissi Rodion V Belosludov Oleg S Subbotin Hiroshi Mizuseki Yoshiyuki Kawazoe Vladimir R Belosludov
Publish Date: 2010/08/20
Volume: 69, Issue: 1-2, Pages: 281-286
Abstract
The thermodynamic properties of propane clathrate hydrate with cubic structure IV were studied using a method based on the solid solution theory of van der Waals and Platteeuw but allows one to take into account the influence of guest molecules on the host lattice and guestguest interactions The free energies equations of state and chemical potentials of this hydrate were estimated using this approach The proposed theory was used for construction of “guest gas–hydrate–ice I h ” equilibrium curves of propane hydrates It was found that the water framework of structure IV was dynamically stable and that the fully C3H8 filled structure was thermodynamically stable in the region of pressure from 43 to 50 MPa as compared with the hexagonal ice The formation pressure of propane hydrate with structure IV is higher than that of propane hydrate with cubic structure II However a structural transformation from structure II to IV of propane hydrate was estimated under a pressure of 78 MPa at 290 KWe would like to thank the New Energy and Industrial Technology Development Organization NEDO for supporting this work The authors are also grateful for the continuous support of the HITACHI SR 11000K2/51 supercomputing facility at the Institute for Materials Research Tohoku University MS also thanks the Ministry of Higher Education and Scientific Research of Tunisia as well as the GCOE program for financial support
Keywords:
.
|
Other Papers In This Journal:
- Cytosine: para -sulphonato-calix[4]arene assemblies: in solution, in the solid-state and on the surface of hybrid silver nanoparticles
- β-Cyclodextrin/protein conjugates as a innovative drug systems: synthesis and MS investigation
- Pre-formulation of an oral cyclosporine free of surfactant
- Vibrational dynamics and hydrogen bond properties of β-CD nanosponges: an FTIR-ATR, Raman and solid-state NMR spectroscopic study
- Improved aqueous Cannizzaro reaction in presence of cyclodextrin
- The solid-state structures of the ethanol solvated complexes of para -sulphonato-calix[4]arene with magnesium and calcium ions
- Design and evaluation of folate-appended methyl-β-cyclodextrin as a new antitumor agent
- 8-Hydroxyquinoline Based Multipodal Systems: Effect of Spatial Placement of 8-Hydroxyquinoline on Metal Ion Recognition
- Thiacalixarenes: emergent supramolecules in crystal engineering and molecular recognition
- Synthesis and characterization of new organocobaloxime derivatives with asymmetric dioxime ligands
- Encapsulation and Release Characteristics of Carbon Dioxide in α-Cyclodextrin
- Molecular dynamics simulation and quantum chemical studies on the investigation of aluminum nitride nanotube as phosgene gas sensor
- Synthesis, structure and property of three divalent metal complexes of the piperidinoacetyl-containing calix[4]arene
- In vitro evaluation of the cytotoxicity of a folate-modified β-cyclodextrin as a new anti-cancer drug delivery system
- Sorption onto insoluble β-cyclodextrin polymer for 2,4-dinitrophenol
- Glycation of human serum albumin affects its binding affinity towards (−)-epigallocatechin gallate
- Organotellurium-bridged cyclodextrin dimers as artificial glutathione peroxidase models
- Interactions of cyclodextrins with aromatic amino acids: a basis for protein interactions
- Naphthyridine amide–urea conjugate: a case toward selective fluorometric sensing of N -acetyl proline carboxylate
- A novel switch-on fluorescent receptor for bromide based on an amide group
- Thermodynamics of ZrO 2+ cation complexation with dibenzo-18-crown-6 in mixed non-aqueous solvents
- A computational study of hydrogen cyanide interaction with the pristine and B, Ga, BGa-doped of (8, 0) zigzag AlPNTs
- Selective Pseudo-Rotaxane Type Complex Formation of Zinc(II) ( t -butylatedtetraphenyl) porphyrin-Viologen Linked Compounds with tri- O -methyl-β-Cyclodextrin
- Controlled release of antifungal volatiles of thyme essential oil from β-cyclodextrin capsules
- Synthesis, crystal structure and spectroscopic studies of copper(II) complex of C -meso-1,5,8,12-tetramethyl-1,4,8,11-tetraazacyclotetradecane
- Sorption of azo dyes from aqueous solutions by tetradodecyloxybenzylcalix[4]resorcinarene derivatives
- Preparation and characterization of phospholipid complexes of naringenin for effective drug delivery
- Thermodynamics of cesium complexes formation with 18-crown-6 in ionic liquids
- Determination of the ionization constants of natural cyclodextrins by high-resolution 1 H-NMR and photon correlation spectroscopy
- Monosodium salt of p-tert -butylcalix[4]arene in the reactions with electrophilic reagents. Synthesis and structure of monofunctionalized calix[4]arenes
- Paramagnetic properties and molecular structure of coordination saturated inclusive lanthanide complexes with 18-crown-6 using NMR
- Inclusion complex formation of α- and β-cyclodextrins with aminobenzoic acids in aqueous solution studied by 1 H NMR
- Preparation of a cyclodextrin dimer linked with a bis(picolinyl)cystine moiety and its intra- and intermolecular inclusion behavior
- Machines in art and chemistry
|