Authors: Olexander A Yesypenko Vyacheslav I Boyko Mariia A Klyachina Svitlana V Shishkina Oleg V Shishkin Volodymyr V Pyrozhenko Ivan F Tsymbal Vitaly I Kalchenko
Publish Date: 2012/02/11
Volume: 74, Issue: 1-4, Pages: 265-275
Abstract
Monosodium salt of ptertbutylcalix4arene reacts with alkyl halides or aroyl chlorides in DMF formed the coneshaped monoalkyloxycalix4arenes or 13diacyloxycalix4arenes respectively Diacyloxycalix4arenes are easily transformed into monoacyloxycalix4arenes in the partial cone conformation by interaction with NaOMe The influence of intramolecular hydrogen bonding on course of alkylation and acylation reactions as well as the structure of the synthesized compounds in solution and crystalline state are discussed
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