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Title of Journal: J Incl Phenom Macrocycl Chem

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Abbravation: Journal of Inclusion Phenomena and Macrocyclic Chemistry

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Springer Netherlands

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DOI

10.1002/uog.3947

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ISSN

1573-1111

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The solidstate structures of the ethanol solvated

Authors: Kinga Suwinska Erwann Janneau Yannick Tauran Anthony W Coleman
Publish Date: 2013/06/16
Volume: 79, Issue: 1-2, Pages: 177-183
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Abstract

The structures ethanol solvated complexes of parasulphonatocalix4arene with magnesium and calcium have been determined Both show the classical bilayer structure of parasulphonatocalix4arene The cations are situated between the bilayers In the case of the magnesium complex the cation is octahedrally coordinated by six water molecules however for the calcium complex the cation is coordinated in two different geometries by water molecules bridging oxygen atoms of the sulphonate anions and an oxygen of an ethanol molecule Both complexes contain an ethanol molecule embedded in the macrocyclic cavity

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