Journal Title
Title of Journal: Monatsh Chem
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Abbravation: Monatshefte für Chemie - Chemical Monthly
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Publisher
Springer Vienna
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Authors: H Falk G Haller K Schlögl
Publish Date: 1967/05/01
Volume: 98, Issue: 3, Pages: 592-602
Abstract
Die isomeren Methyl und 11′Dimethylferrocencarbonsäuren — darunter die bisher nicht beschriebene βMethylferrocencarbonsäure — sind durch neue Synthesen in präparativen Mengen zugänglich geworden Von drei untersuchten Wegen erwies sich dieVilsmeierFormylierung von Methyl bzw Dimethylferrocen Umwandlung der Gemische isomerer Aldehyde in die Säuren und deren Auftrennung über die Ester als ergiebigste Ferner wurde zur Darstellung der Säuren über die Alkohole und Aldehyde die Aminomethylierung von Methyl und Dimethylferrocen sowie die Acylierung mit Diphenylcarbamylchlorid herangezogenBy new syntheses the isomeric methyl and 11′dimethylferrocene carboxylic acids including the hitherto unknown βmethylferrocene carboxylic acid are now accessible in preparative quantities Of the routes investigatedVilsmeier formylation of methyl and dimethylferrocene conversion of the mixtures of isomeric aldehydes into the carboxylic acids and separation of the lattervia the esters proved to be the most satisfactory Further synthetic methods employed were the aminomethylation and also acylation with diphenyl carbamylchloride of methyl and dimethylferrocene resp
Keywords:
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- Complexation of Li + with antamanide: an experimental and theoretical study
- Cyclic α -amino acids as precursors for synthesis of 2-amino-3-hetarylpyrrolin-4-ones and their spiro derivatives
- 7,15-Diazadispiro[5.1.5.3]hexadecan und Derivate, 1. Mitt.: Darstellung der Grundkörper
- Reaching for cyclacenes and short nanotubes through Si substitutions as studied by DFT calculations
- Über Dialkylidensulfamide
- Spectrometric methods for determination of ligand–protein ratio in monoclonal conjugates: a mini review
- Carbon–nitrogen nanorings and nanoribbons: a theoretical approach for altering the ground states of cyclacenes and polyacenes
- Methylendiformamid: Ausgangsmaterial für oligomere Carbonsäureamide und-imide
- The scale-up of material microstructuring: from scanning probes to self-assembly
- 4th Young Investigator Workshop
- Mittlere Schwingungsamplituden der Seleninylhalogenide
- Amino Acid Derivatives, VII [1]: Synthesis and Antiviral Evaluation of α-Amino Acid Esters Bearing an Indazole Side Chain
- Intramolecular Diels–Alder cyclization of biodihydroxylated benzoic acid derivatives towards novel heterocyclic scaffolds
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- The Willgerodt-Kindler Reaction in Water: High Chemoselectivity of Benzaldehydes over Acetophenones
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- Theoretical study of cation–π interactions of Li + , Na + , and K + with [6]helicene
- Phthalimide- N -oxyl salts: efficient organocatalysts for facile synthesis of ( Z )-3-methyl-4-(arylmethylene)-isoxazole-5(4 H )-one derivatives in water
- Synthesis, Analgesic, and Antiparkinsonian Profiles of Some Pyridine, Pyrazoline, and Thiopyrimidine Derivatives
- Expedient approach for the synthesis of novel indenothiophene derivatives
- Nitroacetylene as dipolarophile in [2 + 3] cycloaddition reactions with allenyl-type three-atom components: DFT computational study
- Synthesis of 3-(quinoxalin-2-yl)-2 H -chromen-2-ones under microwave irradiation
- Exploring the Limits of Emulsion Polymerization of Styrene for the Synthesis of Polymer Nanoparticles
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- Diastereoselective syntheses of ( Z )- and ( E )-3-styrylquinolin-4(1 H )-ones
- Thermodynamics of oxygen in dilute liquid silver–tellurium alloys
- Switching central trinucleotide sequences of DNA heptamer regulates adsorption on mercury electrode
- Development of a metal-island-coated swelling/shrinking copolymer sensor for measurement of divalent metal ions
- Phase relations in the Nb–Ni–Cr system at 1,100 °C
- Preparation of an improved sulfonated carbon-based solid acid as a novel, efficient, and reusable catalyst for chemoselective synthesis of 2-oxazolines and bis-oxazolines
- Editorial
- Synthesis, characterization, and anticancer properties of ferrocenyl complexes containing a salicylaldehyde moiety
- A single-step, mild, neutral, catalyst-free method for cyanohydrin synthesis
- Synthesis of a C-2 Stapled Bis-Lexitropsin
- Mechanistic insight into the formation of cinnamates in phosphine-free Heck reactions
- Zur Darstellung von Imidazolidin-thionen-(4) und Imidazolin-(3)-thionen-(5)
- Alkoxycarbonylpiperidines as N-nucleophiles in the palladium-catalyzed aminocarbonylation
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