Journal Title
Title of Journal: Monatsh Chem
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Abbravation: Monatshefte für Chemie - Chemical Monthly
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Publisher
Springer Vienna
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Authors: H Horn F Huber
Publish Date: 1967/05/01
Volume: 98, Issue: 3, Pages: 771-784
Abstract
Die beiden Reaktionen 1 PbR4+Hac→R3Pbac+HR 2 R3Pbac+Hac→R2Pbac2+HR laufen bei der Umsetzung von PbC2H54 und Essigsäure in wasserfr Toluol bei 60° 80° und 100° als konkurrierende Folgereaktionen 2 Ordnung ab Der Reaktionsablauf wurde durch Titration der Essigsäure mit KOCH3Lösung in wasserfr Medium verfolgt wobei die Geschwindigkeitskonstanten und die Aktivierungsenergien der Reaktionen ermittelt wurdenDuring the reaction of PbC2H54 and acetic acid in anhydrous toluene at 60 80 and 100° C the two reactions 1 and 2 proceed as competitive consecutive second order reactions The reaction was studied by nonaqueous titration of acetic acid with KOCH3solution Rate constants and activation energies have been determined
Keywords:
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