Journal Title
Title of Journal: J Chem Crystallogr
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Abbravation: Journal of Chemical Crystallography
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Authors: Qingli Wang Jinpeng Li Dong Sun Hongwei Hou Hongyun Zhang Yunyin Niu Na Xu
Publish Date: 2008/06/19
Volume: 39, Issue: 1, Pages: 42-
Abstract
The first cluster complex of 13bis4pyridinylcarbonyl2imidazolidinethione 4bpit with CuI was prepared and characterized Single crystal Xray diffraction analysis established that the compound crystallizes in the monoclinic system space group C2/m with a = 156013 b = 124383 c = 125703Å β = 110023 Z = 4 V = 229188Å3 This compound is also a coordination polymer with onedimensional doubleribbon structure containing the adaptable rhomboid Cu2I2 cluster unit The solutionstate luminescence spectra showed that the highenergy emission may be associated with a ligandtoligand chargetransfer excited stateThe first cluster complex of 13bis4pyridinylcarbonyl2imidazolidinethione 4bpit with CuI was prepared and characterized This compound is also a coordination polymer with onedimensional doubleribbon structure containing the adaptable rhomboid Cu2I2 cluster unit The solutionstate luminescence spectra showed that the highenergy emission may be associated with a ligandtoligand chargetransfer excited state Open image in new windowThis research was funded by the National Natural Science Foundation Grant No 20671083 the Science Foundation for Distinguished Young Scholars of Henan Province Grant Nos 0612002800 64100002800 and the Undergraduate Innovative Test Program of ZZU Grant No 2007CXSY044
Keywords:
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