Journal Title
Title of Journal: J Chem Crystallogr
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Abbravation: Journal of Chemical Crystallography
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Authors: Saeed Ahmad Muhammad Altaf Helen StoeckliEvans Tobias Rüffer Heinrich Lang Muhammad Mufakkar Abdul Waheed
Publish Date: 2010/02/02
Volume: 40, Issue: 8, Pages: 639-645
Abstract
Reactions of NN′diethylthiourea Detu with copperI cyanide and copperI iodide in a 21 M ratio in acetonitrile resulted in the formation of CuDetuCl3·CH3CN05 1 and CuDetu3I 2 respectively In compound 1 each copper atom is coordinated with one sulfur atom of Detu and with one chloride ion forming a centrosymmetric trinuclear core Cu3S3Cl3 that exhibits a Cu–Cu separation of 273835 Ǻ indicating the existence of cuprophilic interactions Complex 2 crystallizes with two independent molecules per asymmetric unit Each copper atom is coordinated with three sulfur atoms of Detu and with one iodide ion in a tetrahedral arrangement
Keywords:
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