Journal Title
Title of Journal: J Chem Crystallogr
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Abbravation: Journal of Chemical Crystallography
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Authors: İbrahim Kani
Publish Date: 2012/06/21
Volume: 42, Issue: 8, Pages: 832-838
Abstract
The centrosymmetric dimer zinc compound ZnHLbpy2H2O2L L = O2CCF26CO2 bpy = 22′bipyridine was obtained through the reaction of ZnClO42·6H2O bpy and perfluorosuberic acid ZnII centre is coordinated by four N atoms from two bpy ligands and two O atoms from a water molecule and monoanionic suberate ligand in a distorted octahedral coordination environment The unit structure contains crystallographically centrosymmetric suberate anion which acts as a bidentate bridging ligand between each cationic monomer complex unit via hydrogen bonding The very strong interaction of hydrogen bonding of hydoxycarbonyl–carboxylate system in solid state has O–H···O 24363 Å O···H = 1256 Å and H···O = 1196 Å These units are also connected to each other via π···π C–H···π C–F···π and F···F stacking interactions C–H···O O–H···O and C–H···F hydrogen bonds giving rise to a multidimensional network The complex is the first reported example of a coordination compound based on both bpy ligands together with perfluorosuberic acid Moreover compound exhibit intense solid state fluorescent emissions at room temperature
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Other Papers In This Journal:
- Structures of Protonated Bis(pyridine-2-yl) Ketone Arylhydrazone Derivatives: [(C 5 H 4 N)(C 5 H 4 NH)C=NNHC 6 H 4 Y] + [X] − (Y,X = 3-O 2 N,Cl: 4-Me,Cl:)
- Hydrogen Bonded 3D Supramolecular Architectures of Three Saccharinate Salts
- Crystal structure of potassium tris[3-(2-pyridyl)pyrazolyl]hydroborate
- X-ray Structure Investigation of 20- O -β- d -glucopyranosyl-20( S )-protopanaxadiol
- Synthesis, X-ray Structure and Photo Chemistry of 2-(Methyl(1-Phenylvinyl)Carbamoyl)Phenyl Acetate
- Crystal and Molecular Structures of Di-1-Adamantylthiophosphinic Chloride, P , P -Diphenyl- N -Benzyl Phosphinothioic- and Selenoic- Amides
- Crystal structures of 2-pyrazinecarboxylato silver(I) and ammine 2,3-pyrazinecarboxylato disilver(I)
- Syntheses, Characterizations and Crystal Structures of Two Copper Coordination Polymers Both Having Cu 2 Cl 2 Bridging Subunit [Cu I (bipy) 1/2 Cl] n (1) and {[(Cu II ) 4 (phen) 4 (SSA) 2 Cl 2 ](H 2 O) 2 (DMF) 2 } n (2)
- Crystal Structure, Absolute Configuration, Conformational Analysis and Molecular Dynamics Study of the Novel Steroidal Tetrazole Derivative: (25 R )-3,12a-diaza-A,C-bishomo-5α-spirostano[3,4- d ] [12a,12 d ] bistetrazole [HS-989]
- The Role of Halogen Bonding in Crystal Structures of 3-Halogeno Cytisine Derivatives
- Intermolecular Interactions in Dihydrothymine Derivatives Form Two-Dimensional and Three-Dimensional Networks
- Crystallographic and luminescence studies of ammonium and water adducts of anthraquinone fluorophores
- The Crystal Structure and Cytotoxicity of Centrosymmetric Copper(II) Complex Derived from S-methyldithiocarbazate with Isatin
- Dielectric Phase Transition Behavior in an N-salicyliden Based Ion Crystal
- Poly (Isonicotinic Acid N-Oxide–Isonicotinate-N-Oxide-Chloro-Uranyl): The Interpenetrating Grids Created by Coordination and Hydrogen Bonds
- Crystal Structure of a Mixed-Ligand Cu(II) Complex Forming Supramolecular Assembly via an Extensive H-Bonding and Ring–Ring π–π Interactions
- Crystal Structures of 2-Phenyl-2 H -1,2,3-Triazol-4-Carbaldehyde, an Active α-Glycosidase Inhibition Agent, and (1-Phenyl-1 H -1,2,3-Triazol-4-yl)Methyl Benzoate and (2-(4-Fluorophenyl)-2 H -1,2,3-Triazole-4-yl)Methanol, Two Moderately Active Compounds
- Structure of 4-amino-3-butyl-1,2,4-triazole-5-thione: Relation to derivatives with H, Me, Et, and Pr in the 3-position
- Hydrogen Bonding Ring Patterns of Chiral Dibenzoyltartrate in a Series of Hydrated Ammonium Carboxylate Salts with Chiral 1-Phenylethylammonium
- Crystal Structures of Trinuclear Chlorido( N,N ′-diethylthiourea)copper(I) and a Second Polymorph of Iodidotris( N,N ′-diethylthiourea)copper(I)
- Synthesis and crystal structure of catena -poly[aqua( cis-syn-cis -dicyclohexyl-18-crown-6) tetra(thiocyanato)barium(II) platinum(II)]: [BaPt(NCS) 4 (C 20 H 36 O 6 )(H 2 O)] n
- Synthesis, Crystal Structure and Theoretical Calculations of a Cadmium(II) Coordination Polymer Assembled by 4,4′-Oxydibenzoic Acid and 1,3-Bis(imidazol-1-ylmethyl)-Benzene Ligands
- Synthesis, Characterization and Crystal Structure of N,N ′-di[( E )-1-(2-hydoxyphenyl)methylidene]-2,6-naphthalenedicarbohydrazide
- The Crystal Structure of 3-Epismilagenin Acetate and 23-Oxo-3-epismilagenin Acetate
- A New Coordination Polymer of Zn(II)-btc (H 3 btc = Benzene-1,3,5-tricarboxylic acid) with Protonated Acridine: Synthesis, Crystal Structure and Spectroscopic Properties
- Experimental Electron Density of Ammonium Dihydrogen Phosphate in the Paraelectric as well as Antiferroelectric Phases by the Maximum Entropy Method
- Synthesis, Structural Characterization and Spectroscopic Properties of 1,2-Bis[4-(3,5-dimethyl-1 H -pyrazol-1-yl)-2-oxobutyl]benzene
- Crystal Structure of 9α,11-Epoxy-7α-(methoxycarbonyl)-3-oxo-17α-pregn-4-ene-21,17-carbolactone
- Synthesis, Crystal Structures, Density Functional Theory (DFT) Calculations and Molecular Orbital Calculations of Three New Derivatives of 1 - (phenylsulfonyl)indole
- Synthesis and Crystal Structure of New Heterocyclic Compounds Containing 1,2,3-Triazole Moiety
- 1,3-Bis(4-Pyridinylcarbonyl)-2-Imidazolidinethione and Its First Cluster Complex: Synthesis, Crystal Structure and Luminescence Properties
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