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Title of Journal: J Therm Anal Calorim

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Abbravation: Journal of Thermal Analysis and Calorimetry

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Kluwer Academic Publishers

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1572-8943

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Thermal and structural studies of nanocrystalliza

Authors: M Reben I Wacławska C Paluszkiewicz M Środa
Publish Date: 2007/04/11
Volume: 88, Issue: 1, Pages: 285-289
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Abstract

The influence of fluorine content on the structure and crystallization of oxyfluoride glasses from the Na2O–Al2O3–SiO2–LaF3 system was studied by DTA/DSC XRD FTIR and SEM methods It has been found that the increase in the fluorine content in the structure of oxyfluoride glasses causes the increase of the flexibility of their structure which inhibits the process of crystallization of the silicate aluminium matrix Simultaneously the ability of the glass for LaF3 crystallization which shows a multistage character is increasing Analysis of the local atomic interactions in the structure of glasses has been used to explain the course of the crystallization

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