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Title of Journal: J Therm Anal Calorim

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Abbravation: Journal of Thermal Analysis and Calorimetry

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Springer Netherlands

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DOI

10.1007/978-3-319-31012-1_10

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ISSN

1572-8943

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Thermal behaviour of dimethylgoldIII carboxylate

Authors: A A Bessonov N B Morozova P P Semyannikov S V Trubin N V Gelfond I K Igumenov
Publish Date: 2008/07/02
Volume: 92, Issue: 3, Pages: 751-755
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Abstract

The thermal properties of dimethylgoldIII carboxylates of general formula CH32AuOOCR2 R=methyl 1 tertbuthyl 2 trifluoromethyl 3 or phenyl 4 in solid state have been investigated by the thermogravimetric analysis The temperature dependences of saturated vapour pressure of complexes have been studied by the Knudsen effusion method with mass spectrometric indication The thermodynamic parameters Δsub H T 0 and Δsub S T 0 of the sublimation processes have been calculated Thermal decomposition of the vapour of complexes 1 and 2 has been studied by means of high temperature mass spectrometry in vacuum and byproducts of decomposition have been determined

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