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Title of Journal: J Therm Anal Calorim

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Abbravation: Journal of Thermal Analysis and Calorimetry

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Springer Netherlands

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1572-8943

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Molecular complex formation between Emphasis Type

Authors: T R Usacheva I V Chernov V A Sharnin S I Voronina E Matteoli
Publish Date: 2012/12/18
Volume: 112, Issue: 1, Pages: 399-405
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Abstract

The standard thermodynamic parameters Δr G° Δr H° TΔr S° of the reaction of molecular complex formation between 18crown6 ether 18C6 and lphenylalanine Phe Phe18C6 have been obtained from calorimetric titration experiments carried out by means of the microcalorimetric system TAM III TA Instruments USA at T = 29815 K in water–dimethylsulfoxide H2O–DMSO solvents Results show that the increase of the DMSO concentration in the mixed solvents brings about an increase of the Phe18C6 complex stability and of the exothermicity of the reaction of complex formation

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