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Title of Journal: Nuov Cim A

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Abbravation: Il Nuovo Cimento A (1965-1970)

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Società Italiana di Fisica

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DOI

10.1007/s10780-013-9181-3

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1826-9869

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A redefinition of quantummechanical exchange and

Authors: T W Barrett
Publish Date: 2008/01/07
Volume: 50, Issue: 1, Pages: 53-64
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Abstract

In previous papers a deterministic account of the dynamics underlying i the Schrödinger equation ii the commutation relations of quantum theory and Plancks constant and iii theSmatrix and the Klauder phenomenon was presented In the present paper that topological analysis is extended to a deterministic interpretation of atomic orbitals valence bonds molecular orbitals and the electromagnetic field It is demonstrated that atomic orbitals may be considered askjets or the polynomial consisting of all terms of order less than or equal tok in the Taylor expansion of a potential function The electromagnetic field is described in terms of a mapping of two sets of four Clebsch potentials defined on a fourdimensional Riemannian spacetime manifold onto a threedimensional Euclidean space Rund The Clebsch potentials are related to the four parameters used in the quantummechanical orbital descriptionВ предыдущих работах было предложено детерминистическое описание динамики на основе 1 уравнения Шредингера 2 коммутационных соотношений квантовой теории и постоянной Планка и 3Sматрицы и явления Клаудера В этой статье топологический анализ обобщается на детерминистическую интерпретацию атомных орбиталей валентных связей молекулярных орбиталей и электромагнитного поля Показывается что атомные орбитали можно рассматривать какkструи или как полином содержаший члены всех порядков меньших или равныхk в разложении Тейлора потенциальной функции Электромагнитиое поле определяется посредством отображения двух систем четырех потенциалов Клебша определенных на четырехмерном Римановом пространственновременном множестве на трехмерное звклидово пространство Потенциалы Клебша связаны с четырьмя параметрами используемыми при квантовомеханическом описании орбиталейIn un lavoro precedente è stata presentata una descrizione deterministica della dinamica soggetta a i lequazione di Schrödinger ii le relazioni di commutazione della teoria quantistica e la costante di Planck e iii la matriceS e il fenomeno di Klauder Nel presente lavoro quellanalisi topologica è estesa ad uninterpretazione deterministica degli orbitali atomici legami di valenza orbitali molecolari e del campo eletromagnetico Si è dimostrato che gli orbitali atomici possono essere considerati come gettik o come polinomi formati da tutti i termini di ordine minore o uguale ak nello sviluppo di Taylor di una funzione del potenziale Si descrive il campo elettromagnetico in termini di una mappatura di due gruppi di 4 potenziali di Clebsch definitisu una molteplicità spaziotemporale quadridimensionale di Riemann in uno spazio cuclideo tridimensionale Rund I potenziali di Clebsch sono correlati ai quattro parametri usati nella descrizione quantomeccanica degli orbitali


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