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Title of Journal: Journal of Elec Materi

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Abbravation: Journal of Electronic Materials

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Springer US

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DOI

10.1016/0020-0891(89)90035-3

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1543-186X

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GadoliniumActivated CaZrSubscript4/SubscriptO

Authors: Vijay Singh N Singh S Watanabe T K Gundu Rao M S Pathak A K Srivastava P K Singh S J Dhoble
Publish Date: 2017/02/06
Volume: 46, Issue: 4, Pages: 1943-1947
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Abstract

Gadoliniumactivated CaZr4O9 ultravioletBemitting phosphor has been prepared by a solution combustion method and characterized using powder xray diffraction analysis electron paramagnetic resonance EPR and photoluminescence PL spectroscopic techniques Upon excitation at 274 nm the emission spectrum exhibits a welldefined ultraviolet B emission band with maximum at 313 nm corresponding to 6P7/2 → 8S7/2 transition A characteristic “U”type EPR spectrum is observed for the powder samples Doped Gd3+ ion appears to occupy calcium sites in the phosphor lattice EPR and PL analyses of the sample confirm presence of Gd3+ in the CaZr4O9 host

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